Synthesis and structure of [{(But;O)2Sb3(μ-NCy)3(μ3-NCy)}K.η6-C6H5Me];: a sandwich complex containing a unique SbIII nido cage anion (Cy=cyclohexyl, C6H11)

被引：12

作者：

Beswick, MA

Choi, N

Hopkins, AD

McPartlin, M

Paver, MA

Wright, DS

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

[2] Univ N London, Sch Appl Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 02期

关键词：

D O I：

10.1039/a708083b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the terminal NMe2 groups of the spiro antimony(III) imido anion [{(Me2N)Sb(mu-NCy)}(2)Sb](-) with (BuOH)-O-t results in major rearrangement in the Sb-N framework as witnessed in the structure of the sandwich complex [{((BuO)-O-t)(2)Sb-3(mu-NCy)(3)(mu(3)-NCy)}K .eta(6)-C6H5Me] 1, containing the novel nido cage anion [((BuO)-O-t)(2)Sb-3(mu-NCy)(3)(mu(3)-NCy)](-).

引用

页码：261 / 262

页数：2

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