A novel liquid-crystalline vinylcyclopropane-derivative bearing cholesterol: Synthesis and polymerization

被引：6
|
作者：
Casper, P [1 ]
Ritter, H [1 ]
机构：
[1] Univ Dusseldorf, Inst Organ Chem & Makromol Chem, Lehrstuhl 2, D-40225 Dusseldorf, Germany
来源：
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 2003年 / A40卷 / 02期
关键词：
liquid-crystalline polymer (LCP); ring-opening polymerization; 2-vinylcyclopropane;
D O I：
10.1081/MA-120017254
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of a liquid-crystalline vinycyclopropane, 1-ethoxycarbonyl-1-[5-(cholesteryloxycarbonyl)pentoxycarbonyl]-2-vinylcyclopropane (4), and its polymerization is described. The polymerization of 4 was carried out in toluene as solvent and with AIBN as free radical initiator at 70degreesC. The obtained polymer also showed liquid-crystalline behavior similar to that of the monomer 4.
引用
收藏
页码：107 / 113
页数：7
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