[2-(3,5-Dibromo-2-oxidobenzylamino)-3-phenyl-propanoato-κ3 N,O,O′](1,10-phenanthroline-κ2N,N′)zinc(II) dihydrate

被引：3

作者：

Zhang, Shu-Hua ^{[1
]}

Feng, Xiao-Zhen ^{[1
]}

Li, Guang-Zhao ^{[1
]}

Jing, Li-Xia ^{[1
]}

Liu, Zheng ^{[1
]}

机构：

[1] Guilin Univ Technol, Minist Educ, Key Lab Non Ferrous Met Mat & Proc Technol, Dept Mat & Chem Engn, Guilin 541004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807000177

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Zn(C16H13Br2NO3)(C12H8N2)].2H(2)O or [Zn(L)(phen)].2H(2)O, [LH2 = 2-(3,5-dibromo-2-hydroxybenzylamino)-3-phenylpropionic acid and phen = 1,10-phenanthroline], the Zn-II atom is coordinated in a slightly distorted square-pyramidal geometry by two O atoms and one N atom from an L2- ligand and two N atoms from a phen ligand. One of the carboxylate O atoms is in the apical position. In the crystal structure, complex molecules are linked into a chain along the c axis through N-H...O hydrogen bonds; the water molecules are connected to the chains via O-H...O hydrogen bonds.

引用

页码：M396 / M398

页数：3

共 12 条

[1]

*BRUK AXS INC, 2004, SMART VERS 6 36 SAIN

[2] COORDINATION MODES OF HISTIDINE .9. SYNTHESIS, STEREOCHEMISTRY, AND OXYGENATION OF COBALT(II)-PYRIDOXAL MODEL COMPLEXES - A NEW FAMILY OF CHIRAL DIOXYGEN CARRIERS [J].