Synthesis, Crystal Structure and Cyclic Voltametric Property of Cu(II) Complex with 4,4′-Bipy and α-Pyridine Carboxylate

被引：0
|
作者：
Wu Gang [1 ]
Wang Xiao-Feng [2 ]
Xian Hua [2 ]
Guo Xue-Lin [1 ]
机构：
[1] Chuzhou Univ, Dept Chem & Life Sci, Chuzhou 239012, Anhui, Peoples R China
[2] Xiao Zhuang Univ, Biochem & Environm Engn Coll, Nanjing 211171, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 07期
关键词：
copper(II) complex; 4,4 '-bipyridine; cyclic voltametry; NETWORKS;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [Cu(bipy)(pc)(H2O)(ClO4)]center dot H2O (1) (bipy: 4,4'-bipyridine; Hpc: alpha-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis. It crysrallizes in the Monoclinic space group P2(1)/n. The crystal structure reveals that Cu(II) centre adopts a pseudo octahedral geometry. Ligand 4,4'-bipyridine as a bridge coordinates to two different Cu(II) center to form a one-dimensional zigzag chain. One dimensional chains are linked by C-H center dot center dot center dot O hydrogen bonding interactions to form two-dimensional layer. Layers are connected by O center dot center dot center dot H-O hydrogen bond to generate three-dimensional structure. The cyclic voltametric behavior of complex 1 is also investigated. CCDC: 743537.
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页码：1315 / 1318
页数：4
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