Controlling Topology within Halogen-Bonded Networks by Varying the Regiochemistry of the Cyclobutane-Based Nodes

被引：5

作者：

Dunning, Taylor J. ^{[1
]}

Unruh, Daniel K. ^{[2
]}

Bosch, Eric ^{[3
]}

Groeneman, Ryan H. ^{[1
]}

机构：

[1] Webster Univ, Dept Biol Sci, St Louis, MO 63119 USA

[2] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA

[3] Missouri State Univ, Dept Chem, Springfield, MO 65897 USA

来源：

MOLECULES | 2021年 / 26卷 / 11期

关键词：

halogen bonding; crystal engineering; organic solid state; topology; 2+2 CYCLOADDITION REACTION;

D O I：

10.3390/molecules26113152

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The formation of a pair of extended networks sustained by halogen bonds based upon two regioisomers of a photoproduct, namely rctt-1,3-bis(4-pyridyl)-2,4-bis(phenyl)cyclobutane (ht-PP) and rctt-1,2-bis(4-pyridyl)-3,4-bis(phenyl)cyclobutane (hh-PP), that have varied topology is reported. These networks are held together via IMIDLINE HORIZONTAL ELLIPSISN halogen bonds between the photoproduct and the halogen-bond donor 1,4-diiodoperchlorobenzene (C6I2Cl4). The observed topology in each solid is controlled by the regiochemical position of the halogen-bond accepting 4-pyridyl group. This paper demonstrates the ability to vary the topology of molecular networks by altering the position of the halogen bond acceptor within the cyclobutane-based node.

引用

页数：8

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