Reactivity of metal-containing monomers - 48. Thermal transformations of cobalt(II) maleate

被引：6

作者：

Rosenberg, AS ^{[1
]}

Aleksandrova, EI ^{[1
]}

Ivleva, NP ^{[1
]}

Dzhardimalieva, GI ^{[1
]}

Raevskii, AV ^{[1
]}

Kolesova, OI ^{[1
]}

Uflyand, IE ^{[1
]}

Pomogailo, AD ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 02期

关键词：

metal carboxylates; thermolysis; solid-phase polymerization; nano-size particles; stabilization;

D O I：

10.1007/BF02498945

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal conversion of cobalt(II) maleate, CoC4H2O4 . 2H(2)O, (1) at 340-370 degrees C was studied. The composition of the products of pyrolysis was determined. The major solid-phase product of decomposition consists of nano-sized particles of CoO (sizes vary within narrow limits) stabilized by the polymeric matrix. Thermal conversions of Co-II maleate involve dehydration, polymerization of dehydrated monomers, and decarboxylation of the resulting polymer.

引用

页码：259 / 264

页数：6

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