A Highly Efficient Bismuth Nitrate/Keto-ABNO Catalyst System for Aerobic Oxidation of Alcohols to Carbonyl Compounds under Mild Conditions

被引：6

作者：

Hu, Yongke ^{[1
]}

Chen, Lei ^{[2
]}

Shen, Gulou ^{[1
]}

Li, Jin ^{[1
]}

Li, Shaozhong ^{[1
]}

Li, Huaju ^{[1
]}

Li, Yanxing ^{[1
]}

机构：

[1] Huaiyin Inst Technol, Natl & Local Joint Engn Res Ctr Mineral Salt Deep, Huaian 223003, Peoples R China

[2] Nanjing Normal Univ, Zhongbei Coll, Zhenjiang 212300, Jiangsu, Peoples R China

来源：

MOLECULES | 2022年 / 27卷 / 12期

基金：

中国国家自然科学基金;

关键词：

carbonyl compounds; aerobic oxidation; bismuth nitrate; keto-ABNO; RECYCLABLE CATALYST; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; MOLECULAR-OXYGEN; ALDEHYDES/KETONES; QUINAZOLINONES; KETONES; AIR;

D O I：

10.3390/molecules27123727

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

An efficient and practical catalytic system for the oxidation of alcohols to aldehydes/ketones using catalytic amounts of Bi(NO3)(3) and Keto-ABNO (9-azabicyclo [3.3.1]nonan-3-one N-oxyl) with air as the environmentally benign oxidant was developed. Various primary and secondary alcohols were smoothly oxidized to the corresponding products under mild conditions, and satisfactory yields were achieved. Moreover, this methodology avoids the use of a ligand and base. The gram-scale reaction was demonstrated for the oxidation of 1-phenyl ethanol, and the product of acetophenone was obtained at an isolated yield of about 94%.

引用

页数：8

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