Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

被引：36

作者：

Adly, Frady G. ^{[1
]}

Ghanem, Ashraf ^{[1
]}

机构：

[1] Univ Canberra, Fac ESTEM, Chiral program, Canberra, ACT 2601, Australia

来源：

CHIRALITY | 2014年 / 26卷 / 11期

关键词：

dirhodium(II) carboxylates; dirhodium(II) carboxamidates; asymmetric; cyclopropanation; cyclopropenation; paddlewheel; METAL CARBENE TRANSFORMATIONS; ALKYL-ALPHA-DIAZOESTERS; C-H INSERTION; INTERMOLECULAR CYCLOPROPANATION REACTIONS; GENERATED PHENYLIODONIUM YLIDE; CONTAINING NATURAL-PRODUCTS; BRIDGING PROLINATE LIGANDS; BOND-FORMING REACTIONS; ENANTIOSELECTIVE SYNTHESIS; RH(II)-CATALYZED CYCLOPROPANATION;

D O I：

10.1002/chir.22347

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed. Chirality 26:692-711, 2014. (c) 2014 Wiley Periodicals, Inc

引用

页码：692 / 711

页数：20

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