Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

被引：36
作者：
Adly, Frady G. [1 ]
Ghanem, Ashraf [1 ]
机构：
[1] Univ Canberra, Fac ESTEM, Chiral program, Canberra, ACT 2601, Australia
来源：
CHIRALITY | 2014年 / 26卷 / 11期
关键词：
dirhodium(II) carboxylates; dirhodium(II) carboxamidates; asymmetric; cyclopropanation; cyclopropenation; paddlewheel; METAL CARBENE TRANSFORMATIONS; ALKYL-ALPHA-DIAZOESTERS; C-H INSERTION; INTERMOLECULAR CYCLOPROPANATION REACTIONS; GENERATED PHENYLIODONIUM YLIDE; CONTAINING NATURAL-PRODUCTS; BRIDGING PROLINATE LIGANDS; BOND-FORMING REACTIONS; ENANTIOSELECTIVE SYNTHESIS; RH(II)-CATALYZED CYCLOPROPANATION;
D O I：
10.1002/chir.22347
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter- and intramolecular asymmetric cyclopropanation, as well as cyclopropenation reactions are discussed. Chirality 26:692-711, 2014. (c) 2014 Wiley Periodicals, Inc
引用
收藏
页码：692 / 711
页数：20
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