Versatile catalysis of iron: tunable and selective transformation of biomass-derived furfural in aliphatic alcohol

被引：31
作者：
Zhang, Zhenya [1 ]
Tong, Xinli [1 ]
Zhang, Haigang [1 ]
Li, Yongdan [2 ]
机构：
[1] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin Key Lab Organ Solar Cells & Photochem Con, Tianjin 300384, Peoples R China
[2] Tianjin Univ, Sch Chem Engn, Tianjin 300072, Peoples R China
来源：
GREEN CHEMISTRY | 2018年 / 20卷 / 13期
基金：
中国国家自然科学基金;
关键词：
OXIDATIVE CONDENSATION; PLATFORM CHEMICALS; HYDROCARBON FUELS; MOLECULAR-OXYGEN; NI-B; HYDROGENATION; CONVERSION;
D O I：
10.1039/c8gc00852c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An iron-catalyzed efficient valorization of biomass-derived furfural (FUR) in aliphatic alcohols is developed in which product selectivity can be simply regulated by varying the gas atmosphere. In the presence of molecular oxygen, there is oxidative condensation of FUR with ethanol, and the obtained product is furan-2-acrolein in a "FUR-ethanol-O-2" system. Under suitable conditions, the conversion of FUR and selectivity of furan-2-acrolein are 84.2% and 82.7%, respectively. In the presence of H-2, the selective hydrogenation of FUR is achieved, and the main product is furfuryl alcohol in a "FUR-ethanol-H-2" system. Under optimal conditions, a 99.9% conversion of FUR and 93.6% selectivity of furfuryl alcohol are attained. This provides an economic, green and sustainable method for the utilization of biomass-based platform compounds in the chemical industry.
引用
收藏
页码：3092 / 3100
页数：9
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