Versatile catalysis of iron: tunable and selective transformation of biomass-derived furfural in aliphatic alcohol

被引：32

作者：

Zhang, Zhenya ^{[1
]}

Tong, Xinli ^{[1
]}

Zhang, Haigang ^{[1
]}

Li, Yongdan ^{[2
]}

机构：

[1] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin Key Lab Organ Solar Cells & Photochem Con, Tianjin 300384, Peoples R China

[2] Tianjin Univ, Sch Chem Engn, Tianjin 300072, Peoples R China

来源：

GREEN CHEMISTRY | 2018年 / 20卷 / 13期

基金：

中国国家自然科学基金;

关键词：

OXIDATIVE CONDENSATION; PLATFORM CHEMICALS; HYDROCARBON FUELS; MOLECULAR-OXYGEN; NI-B; HYDROGENATION; CONVERSION;

D O I：

10.1039/c8gc00852c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An iron-catalyzed efficient valorization of biomass-derived furfural (FUR) in aliphatic alcohols is developed in which product selectivity can be simply regulated by varying the gas atmosphere. In the presence of molecular oxygen, there is oxidative condensation of FUR with ethanol, and the obtained product is furan-2-acrolein in a "FUR-ethanol-O-2" system. Under suitable conditions, the conversion of FUR and selectivity of furan-2-acrolein are 84.2% and 82.7%, respectively. In the presence of H-2, the selective hydrogenation of FUR is achieved, and the main product is furfuryl alcohol in a "FUR-ethanol-H-2" system. Under optimal conditions, a 99.9% conversion of FUR and 93.6% selectivity of furfuryl alcohol are attained. This provides an economic, green and sustainable method for the utilization of biomass-based platform compounds in the chemical industry.

引用

页码：3092 / 3100

页数：9

共 34 条

[1] Catalytic conversion of biomass to biofuels [J].

Alonso, David Martin ;

Bond, Jesse Q. ;

Dumesic, James A. .

GREEN CHEMISTRY, 2010, 12 (09) :1493-1513

[2]

[Anonymous], 2007, ULLMANNS ENCY IND CH

[3] Catalytic conversion of furfural to industrial chemicals over supported Pt and Pd catalysts [J].

Bhogeswararao, S. ;

Srinivas, D. .

JOURNAL OF CATALYSIS, 2015, 327 :65-77

[4] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[5] INDUSTRIAL DEVELOPMENT OF FURFURAL [J].

BROWNLEE, HJ ;

MINER, CS .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (02) :201-204

[6] Catalytic Transfer Hydrogenation of Furfural to 2-Methylfuran and 2-Methyltetrahydrofuran over Bimetallic Copper-Palladium Catalysts [J].

Chang, Xin ;

Liu, An-Feng ;

Cai, Bo ;

Luo, Jin-Yue ;

Pan, Hui ;

Huang, Yao-Bing .

CHEMSUSCHEM, 2016, 9 (23) :3330-3337

[7] Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels [J].

Climent, Maria J. ;

Corma, Avelino ;

Iborra, Sara .

GREEN CHEMISTRY, 2014, 16 (02) :516-547

[8] Hydrodeoxygenation processes: Advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels [J].

De, Sudipta ;

Saha, Basudeb ;

Luque, Rafael .

BIORESOURCE TECHNOLOGY, 2015, 178 :108-118

[9] Current technologies for biomass conversion into chemicals and fuels [J].

Demirbas, M. Fatih .

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2006, 28 (13) :1181-1188

[10] Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals [J].

Deuss, Peter J. ;

Barta, Katalin ;

de Vries, Johannes G. .

CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (05) :1174-1196

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