On the use of double-skinned membranes to prevent chemical interaction between membranes and catalysts

被引:6
作者
Arratibel, Alba [1 ]
Tanaka, Alfredo Pacheco [1 ]
van Sint Annaland, Martin [2 ]
Gallucci, Fausto [3 ]
机构
[1] Tecnalia, Energy & Environm Div, Mikeletegi Pasealekua 2, San Sebastian 20009, Spain
[2] Eindhoven Univ Technol, Dept Chem Engn & Chem, Chem Proc Intensificat, Dolech 2,Rondom 70, NL-5612 AP Eindhoven, Netherlands
[3] Eindhoven Univ Technol, Dept Chem Engn & Chem, Sustainable Proc Engn, Inorgan Membranes & Membrane Reactors, Rondom 70, NL-5612 AP Eindhoven, Netherlands
关键词
Pd-based membranes; Double-skin; Hydrogen separation; TiO2; catalyst; WATER-GAS-SHIFT; PT-RE/ZRO2; CATALYSTS; PALLADIUM MEMBRANE; MESOPOROUS TITANIA; PT-RE/TIO2; RUTILE; GOLD CATALYSTS; PD; INTERFACE; MECHANISM; SUPPORT;
D O I
10.1016/j.ijhydene.2019.10.203
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This communication summarizes the use of double-skinned membranes for hydrogen separation in presence of TiO2 based catalyst (PtReCe/TiO2). The use of this type of membrane avoids the direct contact between catalyst particles and surface of the Pd-based hydrogen selective layer due to the presence of a mesoporous YSZ/g-Al2O3 layer. The PdAg layer is protected by the mesoporous layer from direct contact with catalyst particles, avoiding erosion and possible chemical interactions. In comparison with a conventional PdAg membrane, the hydrogen flux of DS-membrane was observed not to be compromised during test carried out at 400 degrees C. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:20240 / 20244
页数:5
相关论文
共 32 条
[1]  
Arratibel A, 2015, MEMBRANE REACTORS AU, P61
[2]   Unravelling the transport mechanism of pore-filled membranes for hydrogen separation [J].
Arratibel, Alba ;
Alfredo Pacheco Tanaka, D. ;
Slater, Thomas J. A. ;
Burnett, Timothy L. ;
Annaland, Martin van Sint ;
Gallucci, Fausto .
SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 203 :41-47
[3]   Development of Pd-based double-skinned membranes for hydrogen production in fluidized bed membrane reactors [J].
Arratibel, Alba ;
Pacheco Tanaka, Alfredo ;
Laso, Iker ;
Annaland, Martin Van Sint ;
Gallucci, Fausto .
JOURNAL OF MEMBRANE SCIENCE, 2018, 550 :536-544
[4]   Recent Advances in Pd-Based Membranes for Membrane Reactors [J].
Arratibel Plazaola, Alba ;
Pacheco Tanaka, David Alfredo ;
Annaland, Martin Van Sint ;
Gallucci, Fausto .
MOLECULES, 2017, 22 (01)
[5]   Role of Re in Pt-Re/TiO2 catalyst for water gas shift reaction:: A mechanistic and kinetic study [J].
Azzam, K. G. ;
Babich, I. V. ;
Seshan, K. ;
Lefferts, L. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 80 (1-2) :129-140
[6]   A bifunctional catalyst for the single-stage water-gas shift reaction in fuel cell applications. Part 2. Roles of the support and promoter on catalyst activity and stability [J].
Azzam, K. G. ;
Babich, I. V. ;
Seshan, K. ;
Lefferts, L. .
JOURNAL OF CATALYSIS, 2007, 251 (01) :163-171
[7]   Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: implications for oxygen-storage properties [J].
Bunluesin, T ;
Gorte, RJ ;
Graham, GW .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 15 (1-2) :107-114
[8]   Effect of Re addition on the WGS activity and stability of Pt/CeO2-TiO2 catalyst for membrane reactor applications [J].
del Villar, V. ;
Barrio, L. ;
Helmi, Arash ;
Annaland, M. Van Sint ;
Gallucci, F. ;
Fierro, J. L. G. ;
Navarro, R. M. .
CATALYSIS TODAY, 2016, 268 :95-102
[9]   Development of thin Pd-Ag supported membranes for fluidized bed membrane reactors including WGS related gases [J].
Fernandez, Ekain ;
Helmi, Arash ;
Coenen, Kai ;
Melendez, Jon ;
Luis Viviente, Jose ;
Pacheco Tanaka, David Alfredo ;
van Sint Annaland, Martin ;
Gallucci, Fausto .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (08) :3506-3519
[10]   Preparation and characterization of composite palladium membranes on sinter-metal supports with a ceramic barrier against intermetallic diffusion [J].
Huang, Yan ;
Dittmeyer, Roland .
JOURNAL OF MEMBRANE SCIENCE, 2006, 282 (1-2) :296-310