Dual-ligand approach for the solvent-free synthesis of indium-based coordination polymers

被引:6
作者
Chen, Dehui [1 ]
Zhong, Yeshuang [1 ]
Zhang, Chunchun [2 ]
Xu, Dingguo [1 ]
Lin, Zhien [1 ]
机构
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China
[2] Sichuan Univ, Analyt & Testing Ctr, Chengdu 610064, Sichuan, Peoples R China
关键词
Solvent-free synthesis; Coordination polymer; Crystal structure; Indium glutarate; Fluorescent property; METAL-ORGANIC FRAMEWORKS; IONOTHERMAL SYNTHESIS; PHOSPHATE-OXALATES; SULFATE-OXALATES; TOPOLOGIES; CHEMISTRY; CRYSTAL; DESIGN; CHAIN;
D O I
10.1016/j.inoche.2018.04.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three indium-based coordination polymers, formulated as In-2(glu)(3)(2,2'-bpy)(2) (1), In(glu)(Hglu)(phen) (2), and In(glu)(Hglu)(4,4'-bpy) (3), were prepared under solvent-free conditions, where H(2)glu = glutaric acid, 2,2'-bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline, and 4,4'-bpy = 4,4'-bipyridine. Structural analyses reveal that these compounds have ribbonlike, chainlike, and layered architectures, respectively. The fluorescent property of compound 2 was also investigated.
引用
收藏
页码:74 / 77
页数:4
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