Spin-filtering transport and switching effect of MnCu single-molecule magnet

被引：38

作者：

Hao, H.

Zheng, X. H.

Dai, Z. X.

Zeng, Z. ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China

来源：

APPLIED PHYSICS LETTERS | 2010年 / 96卷 / 19期

基金：

美国国家科学基金会;

关键词：

ab initio calculations; copper compounds; Kondo effect; magnetic switching; magnetoelectronics; manganese compounds; molecular electronics; molecular magnetism; organic compounds; MN-12; NANOMAGNETS; MAGNETIZATION;

D O I：

10.1063/1.3430063

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Electron transport of a single-molecule magnet (SMM) device has been investigated using the first-principles calculations. The SMM based device is constructed by a SMM MnCu [MnCuCl(5-Br-sap)2(MeOH)] bridged between semi-infinite Au(100) electrodes with thiol groups connecting the molecule and the gold electrodes. Our results exhibit crucial features of spin filtering and Kondo resonance. The spin filtering remains robust, whereas the Kondo resonance highly depends on the contact geometry. Specifically, this Kondo resonance can be switched on or off by changing the contact distance. The mechanisms of these features are formulated in details. (C) 2010 American Institute of Physics. [doi:10.1063/1.3430063]

引用

收藏

页数：3

相关论文

共 50 条

[21] Quantum Spin Wave Excited from a Cr-Dy Single-Molecule Magnet [J].

Ling, Bo-Kai ;

Chang, Ming ;

Zhai, Yuan-Qi ;

Deng, Jiewei ;

Kofu, Maiko ;

Guo, Hanjie ;

Zhao, Jinkui ;

Fu, Zhendong ;

Zheng, Yan-Zhen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2025, 147 (13) :10935-10942

[22] Analyzing the enforcement of a high-spin ground state for a metallacrown single-molecule magnet [J].

Happ, P. ;

Sapozhnik, A. ;

Klanke, J. ;

Czaja, P. ;

Chernenkaya, A. ;

Medjanik, K. ;

Schuppler, S. ;

Nagel, P. ;

Merz, M. ;

Rentschler, E. ;

Elmers, H. J. .

PHYSICAL REVIEW B, 2016, 93 (17)

[23] Electron-vibron coupling effects on electron transport via a single-molecule magnet [J].

McCaskey, Alexander ;

Yamamoto, Yoh ;

Warnock, Michael ;

Burzuri, Enrique ;

van der Zant, Herre S. J. ;

Park, Kyungwha .

PHYSICAL REVIEW B, 2015, 91 (12)

[24] Spin effects in transport through single-molecule magnets in the sequential and cotunneling regimes [J].

Misiorny, Maciej ;

Weymann, Ireneusz ;

Barnas, Jozef .

PHYSICAL REVIEW B, 2009, 79 (22)

[25] Transport Properties of a Single-Molecule Diode [J].

Loertscher, Emanuel ;

Gotsmann, Bernd ;

Lee, Youngu ;

Yu, Luping ;

Rettner, Charles ;

Riel, Heike .

ACS NANO, 2012, 6 (06) :4931-4939

[26] Heptanuclear cobalt(II) dicubane compounds with single-molecule magnet behavior [J].

Guedes, Guilherme P. ;

Soriano, Stephane ;

Comerlato, Nadia M. ;

Speziali, Nivaldo L. ;

Novak, Miguel A. ;

Vaz, Maria G. F. .

INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 37 :101-105

[27] Origin and spectroscopic determination of trigonal anisotropy in a heteronuclear single-molecule magnet [J].

Sorace, L. ;

Boulon, M. -E. ;

Totaro, P. ;

Cornia, A. ;

Fernandes-Soares, J. ;

Sessoli, R. .

PHYSICAL REVIEW B, 2013, 88 (10)

[28] Redox Switches for Single-Molecule Magnet Activity: An Ab Initio Insight [J].

Vieru, Veacheslav ;

Chibotaru, Liviu F. .

CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (15) :5309-5318

[29] Reversible and controllable switching of a single-molecule junction [J].

Loertscher, Emanuel ;

Ciszek, Jacob W. ;

Tour, James ;

Riel, Heike .

SMALL, 2006, 2 (8-9) :973-977

[30] A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment [J].

Fataftah, Majed S. ;

Zadrozny, Joseph M. ;

Rogers, Dylan M. ;

Freedman, Danna E. .

INORGANIC CHEMISTRY, 2014, 53 (19) :10716-10721

← 1 2 3 4 5 →