One-step preparation of reduced graphene oxide aerogel loaded with mesoporous copper ferrite nanocubes: A highly efficient catalyst in microwave-assisted Fenton reaction

被引：53

作者：

Yao, Tongjie ^{[1
]}

Qi, Yi ^{[2
]}

Mei, Yuqing ^{[2
]}

Yang, Yang ^{[1
]}

Aleisa, Rashed ^{[3
]}

Tong, Xin ^{[2
]}

Wu, Jie ^{[2
]}

机构：

[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China

[2] Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Minist Educ, Harbin 150080, Heilongjiang, Peoples R China

[3] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2019年 / 378卷

基金：

中国国家自然科学基金;

关键词：

Copper ferrite; Graphene oxide; Aerogel; Microwave-assisted Fenton reaction; PHOTOCATALYTIC ACTIVITY; ORGANIC POLLUTANTS; HYDROGEN-PEROXIDE; CARBON NANOTUBES; MAGNETIC CUFE2O4; AQUEOUS-SOLUTION; ELECTRO-FENTON; ALPHA-FEOOH; DEGRADATION; OXIDATION;

D O I：

10.1016/j.jhazmat.2019.05.105

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Heterogeneous Fenton reaction is an attractive method for degradation of organic pollutants due to its high efficiency and non-selectivity and it also causes no secondary pollution. However low degradation rate and poor recyclability of the catalysts limit its applications for water purification. To overcome this herein copper ferrite/reduced graphene oxide (CF/rGO) aerogel was prepared by a one-step hydrothermal method as a highly efficient catalyst for the microwave-assisted Fenton reaction (MAFR). Under optimal conditions (500 W of microwave power 600 mu L of H2O2 15 mg of catalyst and 30 mg/L of RhB) the degradation efficiency of CF/rGO aerogel at 1.0 min (95.7%) was higher than that of reference samples at 3.0 min. Thermodynamical study showed the activation energy enthalpy change entropy change and Gibbs free energy change were 0.73 kJ/mol -49.5 kJ/mol -0.135 kJ/mol K and -6.8 kJ/mol respectively indicating that MAFR was an endothermic and non-spontaneous process.Radical trapping experiments showed that OH O-2(-) and h(+) played a combined role in RhB degradation. Besides high catalytic activity CF/rGO aerogel also displayed good reusability showing removal efficiency of 87.4% after 5 cycles. The high efficiency good reusability and simple process make CF/rGO aerogel a promising catalyst for wastewater treatment.

引用

页数：10

共 45 条

[21] The enhanced method of hydroxyl radical generation in the heterogeneous UV-Fenton system with α-FeOOH as catalyst [J].

Miao, Xiaozeng ;

Dai, Huiwang ;

Chen, Jianxin ;

Zhu, Jianxi .

SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 200 :36-43

[22] Solvothermal synthesis of magnetic copper ferrite nano sheet and its antimicrobial studies [J].

Muthukumar, Krishnan ;

Lakshmi, D. Shanthana ;

Acharya, Saranya D. ;

Natarajan, S. ;

Mukherjee, Amitava ;

Bajaj, H. C. .

MATERIALS CHEMISTRY AND PHYSICS, 2018, 209 :172-179

[23] Heterogeneous Fenton catalysts for the abatement of organic pollutants from aqueous solution: a review [J].

Nidheesh, P. V. .

RSC ADVANCES, 2015, 5 (51) :40552-40577

[24] Synthesis of cubic CuFe2O4 nanoparticles by microwave-hydrothermal method and their magnetic properties [J].

Phuruangrat, Anukorn ;

Kuntalue, Budsabong ;

Thongtem, Somchai ;

Thongtem, Titipun .

MATERIALS LETTERS, 2016, 167 :65-68

[25] Carbon nanotubes as catalysts for catalytic wet peroxide oxidation of highly concentrated phenol solutions: towards process intensification [J].

Pinho, Maria T. ;

Gomes, Helder T. ;

Ribeiro, Rui S. ;

Faria, Joaquim L. ;

Silva, Adrian M. T. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 165 :706-714

[26] Enhanced heterogeneous Fenton-like degradation of methylene blue by reduced CuFe2O4 [J].

Qin, Qingdong ;

Liu, Yahong ;

Li, Xuchun ;

Sun, Tian ;

Xu, Yan .

RSC ADVANCES, 2018, 8 (02) :1071-1077

[27] A comparative study of a series of ferrite nanoparticles as heterogeneous catalysts for phenol removal at neutral pH [J].

Roonasi, Payman ;

Nezhad, Azam Yousef .

MATERIALS CHEMISTRY AND PHYSICS, 2016, 172 :143-149

[28] Comparative studies on the impact of synthesis methods on structural, optical, magnetic and catalytic properties of CuFe2O4 [J].

Selima, S. S. ;

Khairy, M. ;

Mousa, M. A. .

CERAMICS INTERNATIONAL, 2019, 45 (05) :6535-6540

[29]

Simeonidis K, 2016, ENVIRON SCI-WAT RES, V2, P43, DOI [10.1039/c5ew00152h, 10.1039/C5EW00152H]

[30] A novel strategy for the removal of rhodamine B (RhB) dye from wastewater by coal-based carbon membranes coupled with the electric field [J].

Tao, Ping ;

Xu, Yuanlu ;

Song, Chengwen ;

Yin, Yanyan ;

Yang, Zaili ;

Wen, Shihong ;

Wang, Shiyu ;

Liu, Hui ;

Li, Shangzhe ;

Li, Chen ;

Wang, Tonghua ;

Shao, Mihua .

SEPARATION AND PURIFICATION TECHNOLOGY, 2017, 179 :175-183

← 1 2 3 4 5 →