Organic Alloy Electrolytes for Thermostable Solid-State Dye-Sensitized Solar Cells

被引:2
作者
Zhu, Xiaoming [1 ,3 ]
Gui, Yunyun [2 ]
Jiang, Yan [2 ]
Ai, Xinping [2 ]
Yang, Hanxi [2 ]
Cao, Yuliang [1 ,2 ]
机构
[1] Hubei Univ Sci & Technol, Hubei Collaborat Innovat Ctr Nonpower Nucl Techno, Xianning 437100, Peoples R China
[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[3] Hubei Univ Sci & Technol, Sch Nucl Technol & Chem & Bioloy, Xianning 437100, Peoples R China
关键词
Organic alloy; Succinonitrile; Neopentylglycol; Dye-sensitized solar cells; PLASTIC-CRYSTAL ELECTROLYTE; EFFICIENT; PERFORMANCE; CONVERSION;
D O I
10.1016/j.electacta.2014.09.093
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Organic alloy solid electrolytes were prepared based on succinonitrile-neopentylglycol (SCN-NPG) eutectics for Dye-sensitized solar cells (DSSCs). The solid-state electrolytes with the SCN:NPG ratios of 40:60 to 20:80 mol% exhibited a very high conductivity of >2.0 mS cm(-1) at room temperature. The DSSC cell with the organic alloy electrolyte showed highest photoconversion efficiency of 4.4% at 100 mW cm(-2) and a long-term stability as compared with organic liquid or melted plastic electrolytes, offering a low cost, thermostable solid-state electrolyte for commercial development of high efficient dye-sensitized solar cells. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:535 / 539
页数:5
相关论文
共 22 条
  • [1] Conductive organic plastic crystals based on pyrazolium imides
    Abu-Lebdeh, Y
    Alarco, PJ
    Armand, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (37) : 4499 - 4501
  • [2] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies
    Bach, U
    Lupo, D
    Comte, P
    Moser, JE
    Weissörtel, F
    Salbeck, J
    Spreitzer, H
    Grätzel, M
    [J]. NATURE, 1998, 395 (6702) : 583 - 585
  • [3] New fabrication process of long-life dye-sensitized solar cells by in situ gelation of quasi-solid polymer electrolytes
    Chen, Kuei-Fu
    Liu, Chien-Hung
    Hsieh, Chien-Kuo
    Lin, Cian-Li
    Huang, Hsin-Kai
    Tsai, Chuen-Horng
    Chen, Fu-Rong
    [J]. JOURNAL OF POWER SOURCES, 2014, 247 : 939 - 946
  • [4] Rapid I-/I3- diffusion in a molecular-plastic-crystal electrolyte for potential application in solid-state photoelectrochemical cells
    Dai, Q
    MacFarlane, DR
    Howlett, PC
    Forsyth, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (02) : 313 - 316
  • [5] A novel polymer gel electrolyte for highly efficient dye-sensitized solar cells
    Dong, Rui-Xuan
    Shen, Sheng-Yen
    Chen, Hsin-Wei
    Wang, Chun-Chieh
    Shih, Po-Ta
    Liu, Chung-Te
    Vittal, R.
    Lin, Jiang-Jen
    Ho, Kuo-Chuan
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (29) : 8471 - 8478
  • [6] Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids
    Fabregat-Santiago, Francisco
    Bisquert, Juan
    Palomares, Emilio
    Otero, Luis
    Kuang, Daibin
    Zakeeruddin, Shaik M.
    Gratzel, Michael
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (17) : 6550 - 6560
  • [7] Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells
    Grätzel, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) : 3 - 14
  • [8] Long-term stability of dye solar cells
    Harikisun, Ravi
    Desilvestro, Hans
    [J]. SOLAR ENERGY, 2011, 85 (06) : 1179 - 1188
  • [9] Impedance analysis of internal resistance affecting the photoelectrochemical performance of dye-sensitized solar cells
    Hoshikawa, T
    Yamada, M
    Kikuchi, R
    Eguchi, K
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (02) : E68 - E73
  • [10] Highly Efficient Plastic Crystal Ionic Conductors for Solid-state Dye-sensitized Solar Cells
    Hwang, Daesub
    Kim, Dong Young
    Jo, Seong Mu
    Armel, Vanessa
    MacFarlane, Douglas R.
    Kim, Dongho
    Jang, Sung-Yeon
    [J]. SCIENTIFIC REPORTS, 2013, 3