Transition-Metal-Catalyzed Carbon-Carbon Bond Activation in Asymmetric Synthesis

被引：26

作者：

Bi, Xiufen ^{[2
,3
]}

Zhang, Qiuchi ^{[2
,3
]}

Gu, Zhenhua ^{[1
,2
,3
]}

机构：

[1] Minjiang Univ Fuzhou, Ocean Coll, Fuzhou 350108, Fujian, Peoples R China

[2] Univ Sci & Technol China, Ctr Excellence Mol Synth, Hefei Natl Lab Phys Sci Microscale, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China

[3] Univ Sci & Technol China, Ctr Excellence Mol Synth, Dept Chem, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2021年 / 39卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Carbon-carbon activation; Transition-metal; Asymmetric catalysis; Asymmetric synthesis; Ring-opening reaction; C-C BOND; DONOR-ACCEPTOR CYCLOPROPANES; ENANTIOSELECTIVE CYANATION; TERT-CYCLOBUTANOLS; KINETIC RESOLUTION; 3+2 CYCLOADDITION; PALLADIUM; CLEAVAGE; RHODIUM; OLEFINS;

D O I：

10.1002/cjoc.202000591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic asymmetric transformations involving carbon-carbon bond cleavages open intriguing strategies for the synthesis of chiral complex molecules. The transient organometallic species mainly generate from the oxidative addition of cyclic compounds with low valence metals or from beta-carbon elimination of tert-alkoxyl metals. This overview covers the recent advances in transition-metal-catalyzed carbon-carbon bond activation in asymmetric synthesis.

引用

页码：1397 / 1412

页数：16

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