Synthesis of triazole- and pyridine-bridged porphyrin-chlorin and porphyrin dimers

被引：20

作者：

Genady, AR ^{[1
]}

Gabel, D ^{[1
]}

机构：

[1] Univ Bremen, Dept Chem, D-28334 Bremen, Germany

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 14期

关键词：

porphyrin dimer; chlorin; 1,2,4-triazole;

D O I：

10.1016/S0040-4039(03)00468-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 4-amino-1,2,4-triazole linked porphyrin-chlorin dimer and porphyrin dimer is described. New cationic porphyrin dimers were synthesized via the alkylation of the nitrogen atoms of 4,4'-bipyridine and 1,2-di-(4-pyridyl)ethene by meso-monobromomethylporphyrin. These cationic bisporphyrins can interact with DNA and have the ability to cleave it. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2915 / 2917

页数：3

共 7 条

[1] A simple one step synthesis of new 3,5-disubstituted-4-amino-1,2,4-triazoles [J].