A new ruthenium-catalyzed reaction with propargyl alcohol: Cyclopropanation of norbornene

被引：29

作者：

Kikuchi, H ^{[1
]}

Uno, M ^{[1
]}

Takahashi, S ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 567, Japan

来源：

CHEMISTRY LETTERS | 1997年 / 12期

关键词：

COMPLEXES;

D O I：

10.1246/cl.1997.1273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic (eta(5)-cyclopentadienyl)tris(acetonitrile)ruthenium complexes catalyze a new reaction of propargyl alcohol with norbornene in methanol to give a cyclopropanation product, acetyltricyclooctane, in a quantitative yield.

引用

页码：1273 / 1274

页数：2

共 14 条

[1] DIASTEREOSELECTIVE BETA-ELIMINATION - SYNTHESIS OF CHIRAL ALKOXY-ALLENES [J].

ALEXAKIS, A ;

MANGENEY, P ;

NORMANT, JF .

TETRAHEDRON LETTERS, 1985, 26 (35) :4197-4200

[2] CATALYTIC SYNTHESIS OF 3,3-DISUBSTITUTED TRICYCLO[3.2.1.02,4] OCTANES [J].

CATELLANI, M ;

CHIUSOLI, GP .

TETRAHEDRON LETTERS, 1983, 24 (41) :4493-4496

[3] CATALYTIC METHODS FOR METAL CARBENE TRANSFORMATIONS [J].

DOYLE, MP .

CHEMICAL REVIEWS, 1986, 86 (05) :919-939

[4] Synthesis and property of planar-chiral cyclopentadienyl-ruthenium complexes [J].

Komatsuzaki, N ;

Uno, M ;

Kikuchi, H ;

Takahashi, S .

CHEMISTRY LETTERS, 1996, (08) :677-678

[5] ADDITION OF HETEROATOMIC NUCLEOPHILES TO DICARBONYL-ETA-5-CYCLOPENTADIENYL(OLEFIN)IRON CATIONS [J].

LENNON, P ;

MADHAVARAO, M ;

ROSAN, A ;

ROSENBLUM, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 108 (01) :93-109

[6] REACTIONS OF COORDINATED PROPARGYL AND ALLENE LIGANDS IN CYCLOPENTADIENYLIRON DICARBONYL COMPLEXES [J].

LICHTENBERG, DW ;

WOJCICKI, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 94 (02) :311-326

[7]

MITSUDO T, 1994, ANGEW CHEM INT EDIT, V33, P580, DOI 10.1002/anie.199405801

[8] CHIRAL RUTHENIUM(II)-BIS(2-OXAZOLIN-2-YL) PYRIDINE COMPLEXES - ASYMMETRIC CATALYTIC CYCLOPROPANATION OF OLEFINS AND DIAZOACETATES [J].

NISHIYAMA, H ;

ITOH, Y ;

SUGAWARA, Y ;

MATSUMOTO, H ;

AOKI, K ;

ITOH, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (05) :1247-1262

[9] PALLADIUM-CATALYZED REACTIONS OF KETONE ALPHA-CARBONATES WITH NORBORNENES - AN UNUSUAL CYCLOPROPANATION [J].

OGOSHI, S ;

MORIMOTO, T ;

NISHIO, K ;

OHE, K ;

MURAI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (01) :9-10

[10] SYNTHESIS AND CHEMISTRY OF SOME TRICYCLO[4.2.1.02,5]NONANE DERIVATIVES [J].

SAUERS, RR ;

SCHLOSBE.SB ;

PFEFFER, PE .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (06) :2175-+

← 1 2 →