Copper(I)-Catalyzed Synthesis of Polysubstituted Furans from Alkynoates and 1,3-Dicarbonyl Compounds in the Presence of Oxygen

被引:39
作者
Yan, Rulong [1 ]
Huang, Jing [1 ]
Luo, Jia [1 ]
Wen, Ping [1 ]
Huang, Guosheng [1 ]
Liang, Yongmin [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
polysubstituted furans; oxidant; copper catalysis; oxygen; HIGHLY SUBSTITUTED FURANS; ONE-POT SYNTHESIS; CATALYZED CYCLOISOMERIZATION; 2-(1-ALKYNYL)-2-ALKEN-1-ONES; MIGRATION; OXIDATION; ANALOGS; KETONES; SYSTEM;
D O I
10.1055/s-0029-1219778
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel and straightforward synthesis of polysubstituted furans was achieved easily from the oxidative cyclization of 1,3-dicarbonyl compound and alkynoate catalyzed by CuI in the presence of O-2.
引用
收藏
页码:1071 / 1074
页数:4
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