N,N,N′,N′-tetrabutylmalonamide as a new extractant for extraction of nitric acid and uranium(VI) in toluene

被引：13
|
作者：
Wang, YS [1 ]
Sun, GX [1 ]
Bao, BR [1 ]
机构：
[1] Chinese Acad Sci, Inst Nucl Res, Shanghai 201800, Peoples R China
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 1997年 / 224卷 / 1-2期
关键词：
Toluene; Uranium; Adduct; Nitric Acid; HNO3;
D O I：
10.1007/BF02034629
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
N,N,N',N'-tetrabutylmalonamide (TBMA) was synthesized and used for extraction of uranyl(II) ion from nitric acid media in toluene. The effects of nitric acid concentration, extractant concentration, temperature and salting-out agent (LiNO3) on distribution coefficients of uranyl(II) ion have been studied. The extraction of nitric acid is also studied. The main adduct of TBMA and HNO3 is HNO3 TBMA in 1.0 mol/l nitric acid solution. The 1 : 2 : 3 complex of uranyl(II) ion, nitrate ion and TBMA as extracted species is further confirmed by LR spectra of the extraction of uranyl(II) ion with TBMA, and found that the NO3- in the extraction species UO2(NO3)(2) . 3TBMA did not participate in coordination of uranyl(II) ion. The values of thermodynamic parameters have also been calculated.
引用
收藏
页码：151 / 153
页数：3
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