Preparation of Copper Nanoparticles Coated Cotton Fabrics with Durable Antibacterial Properties

被引:44
作者
Xu, Qingbo [1 ]
Ke, Xiating [1 ]
Ge, Naiqin [1 ]
Shen, Liwen [1 ]
Zhang, Yanyan [1 ]
Fu, Feiya [1 ]
Liu, Xiangdong [1 ]
机构
[1] Zhejiang Sci Tech Univ, Coll Mat & Text, Minist Educ, Key Lab Adv Text Mat & Mfg Technol, Hangzhou 310018, Zhejiang, Peoples R China
关键词
Cotton fabric; Surface modification; Copper nanoparticles; Thioglycolic acid; Antimicrobial effect; IN-SITU SYNTHESIS; SILVER NANOPARTICLES; MIST COPOLYMERIZATION; L-CYSTEINE; MECHANICAL-PROPERTIES; SURFACE MODIFICATION; ORGANIC FRAMEWORK; CELLULOSE FIBERS; TERMINAL ALKYNES; AG NANOPARTICLES;
D O I
10.1007/s12221-018-8067-5
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
When copper nanoparticles (Cu NPs) were applied as an antimicrobial agent to finish cotton fabrics, there are two issues should be solved: the oxidization and the weak adsorbability onto cotton fiber surface. In the present work, we developed a new method that can achieve both immobilization and protection of the Cu NPs at the same time. As an effective binder, thioglycolic acid (TGA) was covalently linked to cotton fiber surface via an esterification with the hydroxyl groups of cellulose, then Cu NPs were introduced on the fabric surface in the presence of a protective reagent, citric acid. Due to the doubled stabilization acts of TGA and citric acid, the Cu NPs immobilized on the fabric surface showed an excellent antibacterial effect and outstanding laundering durability. Even after 50 consecutive laundering tests, the modified cotton fabrics still showed satisfactory antibacterial ability against both S. aureus and E. coli, which the bacterial reduction rates are all higher than 96 %. It is believed that this methodology has potential applications in a wide variety of textile productions such as sportswear, socks, and medical textiles.
引用
收藏
页码:1004 / 1013
页数:10
相关论文
共 57 条
[1]   Cu-BTC metal-organic framework natural fabric composites for fuel purification [J].
Abdelhameed, Reda M. ;
Emam, Hossam E. ;
Rocha, Joao ;
Silva, Artur M. S. .
FUEL PROCESSING TECHNOLOGY, 2017, 159 :306-312
[2]   Cu-BTC@cotton composite: design and removal of ethion insecticide from water [J].
Abdelhameed, Reda M. ;
Abdel-Gawad, Hassan ;
Elshahat, Mahmoud ;
Emam, Hossam E. .
RSC ADVANCES, 2016, 6 (48) :42324-42333
[3]   Self-assembled AuNPs for ingrain pigmentation of silk fabrics with antibacterial potency [J].
Ahmed, Hanan B. ;
El-Hawary, Nancy S. ;
Emam, Hossam E. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2017, 105 :720-729
[4]   Layer by Layer Assembly of Nanosilver for High Performance Cotton Fabrics [J].
Ahmed, Hanan B. ;
Emam, Hossam E. .
FIBERS AND POLYMERS, 2016, 17 (03) :418-426
[5]   Synthesis of smart coating for furniture textile and their flammability and hydrophobic properties [J].
Attia, Nour F. ;
Mousa, Mona .
PROGRESS IN ORGANIC COATINGS, 2017, 110 :204-209
[6]   Fabrication of superhydrophobic and antibacterial surface on cotton fabric by doped silica-based sols with nanoparticles of copper [J].
Berendjchi, Amirhosein ;
Khajavi, Ramin ;
Yazdanshenas, Mohammad Esmaeil .
NANOSCALE RESEARCH LETTERS, 2011, 6 :1-8
[7]   Controlled synthesis of copper nano/microstructures using ascorbic acid in aqueous CTAB solution [J].
Bicer, Mustafa ;
Sisman, Ilkay .
POWDER TECHNOLOGY, 2010, 198 (02) :279-284
[8]   Study on Antibacterial and Comfort Performances of Cotton Fabric Finished by Chitosan-silver for Intimate Apparel [J].
Deng, Yong-Mei ;
Wang, Si-Fan ;
Wang, Shang-Jun .
FIBERS AND POLYMERS, 2016, 17 (09) :1384-1390
[9]   Characterization of nanosilver coated cotton fabrics and evaluation of its antibacterial efficacy [J].
El-Rafie, M. H. ;
Ahmed, Hanan B. ;
Zahran, M. K. .
CARBOHYDRATE POLYMERS, 2014, 107 :174-181
[10]   In-situ modification of natural fabrics by Cu-BTC MOF for effective release of insect repellent (N,N-diethyl-3-methylbenzamide) [J].
Emam, Hossam E. ;
Abdelhameed, Reda M. .
JOURNAL OF POROUS MATERIALS, 2017, 24 (05) :1175-1185