A fluorescent chemosensor based on nonplanar donor-acceptor structure for highly sensitive and selective detection of picric acid in water

被引:59
|
作者
Luo, Zijie [1 ]
Liu, Bin [1 ]
Si, Shufan [1 ]
Lin, Yaojin [1 ]
Luo, Crystal Shaojuan [3 ]
Pan, Chengjun [1 ]
Zhao, Chen [2 ]
Wang, Lei [1 ]
机构
[1] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen Key Lab Polymer Sci & Technol, Shenzhen 518060, Peoples R China
[2] South China Agr Univ, Key Lab Nat Pesticide & Chem Biol, Minist Educ, Guangzhou 510642, Guangdong, Peoples R China
[3] Shenzhen Univ, SZU NUS Collaborat Innovat Ctr Optoelect Sci & Te, Shenzhen 518060, Peoples R China
基金
中国国家自然科学基金;
关键词
Chemosensors; Fluorescence; Flavonoid; Picric acid; Water samples; AGGREGATION-INDUCED EMISSION; INTRAMOLECULAR CHARGE-TRANSFER; AQUEOUS-SOLUTION; SOLID-STATE; TRIPHENYLAMINE DERIVATIVES; NITROAROMATIC EXPLOSIVES; SOLVENT POLARITY; TRACE DETECTION; SERUM-ALBUMIN; METAL-IONS;
D O I
10.1016/j.dyepig.2017.05.002
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Direct detection of picric acid in water samples is very important for social security and environmental protection. Herein, a novel donor-acceptor type fluorophore 3-(benzyloxy)-2-(4-(di-p-tolylamino) phenyl)-4H-chromen-4-one has been designed, and synthesized. Due to its aggregation-induced emission enhancement characteristic, this fluorophore showed a very strong fluorescence in water. This fluorophore was then employed as highly sensitive chemosensor for picric acid, with a limit of detection of 370 nM in water. Moreover, this sensor showed very high selectivity towards picric acid among interfering nitroaromatics. At last, the sensing mechanism was carefully studied by using DFT computation and NMR spectra. This work provided a practical and reliable detection method for picric acid in water samples. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:463 / 469
页数:7
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