Synthesis and Characterization of Two of the Three Isomers of a Germanium-Substituted Bicyclo[2.2.0]hexane Diradicaloid: Stretching the Ge-Ge Bond

被引：17

作者：

Wang, Xinping ^{[1
]}

Peng, Yang ^{[1
]}

Zhu, Zhongliang ^{[1
]}

Fettinger, James C. ^{[1
]}

Power, Philip P. ^{[1
]}

Guo, Jingdong ^{[2
]}

Nagase, Shigeru ^{[2
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[2] Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 27期

关键词：

alkyne analogues; bicyclohexanes; digermyne; germanium; nitrosobenzene; THEORETICAL GROUP-14 CHEMISTRY; X-RAY STRUCTURE; DERIVATIVES; REACTIVITY; 1ST;

D O I：

10.1002/anie.201001086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Germane cycles: The inorganic bi- and tricyclohexane derivatives A-C provide novel coordination modes of a nitrosoareneto metals. DFT calculations show that A and B correspond to two of three possible stable isomers of the parent diradicaloid that have different Ge-Ge bond lengths. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4593 / 4597

页数：5