Stereoselective synthesis of functionalized (Z)-keto-enyne and its epoxide

被引：0

作者：

Khan, S

Kato, N

Hirama, M ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

[2] JST, CREST, Sendai, Miyagi 9808578, Japan

来源：

SYNLETT | 2000年 / 10期

关键词：

enynes; epoxides; halides; ring opening; stereoselective synthesis;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method to synthesize (Z)-keto-enyne and its epoxide, possible key intermediates in the total synthesis of maduropeptin chromophore, has been developed through a BuLi-mediated reductive opening of alpha-bromoepoxide.

引用

页码：1494 / 1496

页数：3

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