Stereoselective synthesis of functionalized (Z)-keto-enyne and its epoxide

被引：0
|
作者：
Khan, S
Kato, N
Hirama, M [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
[2] JST, CREST, Sendai, Miyagi 9808578, Japan
来源：
SYNLETT | 2000年 / 10期
关键词：
enynes; epoxides; halides; ring opening; stereoselective synthesis;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method to synthesize (Z)-keto-enyne and its epoxide, possible key intermediates in the total synthesis of maduropeptin chromophore, has been developed through a BuLi-mediated reductive opening of alpha-bromoepoxide.
引用
收藏
页码：1494 / 1496
页数：3
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