Asymmetric base-catalyzed Diels-Alder reaction of 3-hydroxy-2-pyrone with chiral acrylate derivatives

被引：36

作者：

Okamura, H ^{[1
]}

Morishige, K ^{[1
]}

Iwagawa, T ^{[1
]}

Nakatani, M ^{[1
]}

机构：

[1] Kagoshima Univ, Fac Sci, Dept Chem, Kagoshima 890, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(97)10843-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a cinchona alkaloid as a catalyst, the Diels-Alder reaction of 3-hydroxy-2-pyrone with chiral N-acryloyl oxazolidinone afforded a bicyclolactone adduct with high diastereoselectivities (up to 95%de) in almost quantitative yield. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1211 / 1214

页数：4

共 11 条

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