Effect of Iranian traditional cooking on fate of pesticides in white rice

被引:21
作者
Amirahmadi, Maryam [1 ,2 ]
Kobarfard, Farzad [3 ]
Pirali-Hamedani, Morteza [4 ]
Yazdanpanah, Hassan [5 ]
Rastegar, Hossein [1 ,2 ]
Shoeibi, Shahram [1 ,2 ]
Khaneghah, Amin Mousavi [6 ]
机构
[1] Food & Drug Org, Food & Drug Reference Control Labs Ctr, MOH & ME, Tehran, Iran
[2] Food & Drug Org, Food & Drug Lab Res Ctr, MOH & ME, Tehran, Iran
[3] Shahid Beheshti Univ Med Sci, Sch Pharm, Dept Med Chem, Tehran, Iran
[4] Univ Tehran Med Sci, Sch Pharm, Dept Pharmacol, Tehran, Iran
[5] Shahid Beheshti Univ Med Sci, Sch Pharm, Dept Pharmacol & Toxicol, Tehran, Iran
[6] Univ Campinas UNICAMP, Fac Food Engn, Dept Food Sci, Campinas, SP, Brazil
关键词
Cooking; GC; MS; method validation; pesticides; processing factors; white rice; HOME PREPARATION; RESIDUES; REMOVAL; SAMPLES; FOODS;
D O I
10.1080/15569543.2017.1301956
中图分类号
R99 [毒物学(毒理学)];
学科分类号
100405 ;
摘要
In the current study, the reduction in the level of 42 pesticides from different chemical groups in white rice by means of traditional cooking was evaluated. A gas chromatography-mass spectrometry (GC/MS) system in combination with the modified QuEChERS technique as the base of sample preparation method was employed. The spiked rice samples (at 3 levels of 25, 100, and 500ng/g) were analyzed to determine the reduction percentage of pesticide. Processing factor for each pesticide excepted for one of them was lower than 1. The introduced sample preparation and identification methods showed a precision as well as accuracy. The recovery of pesticides at three concentration levels was in the range of 84.08-105.95%. The highest and lowest percentages of pesticides reduction were reported as 99.8% and 15.6% for dichlorvos and metalaxyl, respectively. Regarding the different chemical groups, the most reduction is belong organophosphorus pesticides and the less reduction can be correlated to organochlorine pesticides. The results demonstrated that the Iranian traditional rice cooking, which involves long boiling times, significantly could reduce the concentrations of pesticide residues in white rice.
引用
收藏
页码:177 / 186
页数:10
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