High selective potentiometric sensor for determination of nanomolar con-centration of Cu(II) using a polymeric electrode modified by a graphene/7,7,8,8-tetracyanoquinodimethane nanoparticles

In this paper we present several possibilities for modification of the all-solid-state copper(II)-selective electrodes in order to obtain high stability and selectivity potentiometric sensor signal. The copper(II)-selective electrodes were modified in a simple way by introducing solid contact layer based on graphene or graphene oxide, 7,7,8,8-tetracyanoquinodimethane or its copper salt. Each of electrodes shown a Nernstian response, wide linear range of Cu2+ concentration and a low detection limit. Nevertheless, some differences between the groups of electrodes have been noticed and resulted from application of intermediate layers of various compositions. The electrode modified with graphene and 7,7,8,8-tetracyanoquinodimethane nanocomposite exhibited the best potential reproducibility and detection limit. Moreover, prepared sensors were characterized by an improved selectivity for copper(II) in relation to non-modified electrodes. The developed electrodes were successfully used for the Cu2+ determination in different samples and results were comparable with those obtained using voltammetry.