Reaction of C2H with NO and O2 studied by TR-FTIR emission spectroscopy

被引：31
作者：
Su, HM
Yang, JX
Ding, YH
Feng, WH
Kong, FN [1 ]
机构：
[1] Acad Sinica, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Jilin Univ, Lab Theoret & Computat Chem, Changchun 130023, Jilin, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2000年 / 326卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/S0009-2614(00)00775-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vibrationally excited CO (v), HCO (v(1), v(2)), HNC (v(3)) and HCN (v(3)) were observed as products of the reaction of C2H with NO by using time-resolved FTIR emission spectroscopy. Three exothermic reaction channels leading to HCN + CO, HNC + CO and CN + HCO are identified, verifying an association-elimination reaction mechanism. The nascent products of CO (v less than or equal to 10) and CO2 (v(3), v less than or equal to 3) were observed for the reaction of C2H with O-2. A yield ratio of CO/CO2 is estimated as 9. The experimental observations suggest that reaction is rapid and forms CO and HCO. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：73 / 79
页数：7
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