Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

被引：261

作者：

Davies, Jacob ^{[1
]}

Morcillo, Sara P. ^{[1
]}

Douglas, James J. ^{[2
]}

Leonori, Daniele ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

[2] AstraZeneca, IMED Biotech Unit, Early Chem Dev, Pharmaceut Sci, Macclesfield SK10 2NA, Cheshire, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 47期

基金：

英国工程与自然科学研究理事会;

关键词：

hydroxylamine derivatives; nitrogen radicals; photoredox catalysis; single-electron transfer; visible light; INTRAMOLECULAR HYDROGEN ABSTRACTION; ADDITION CASCADE; AMIDYL RADICALS; GENERATION; AMINATION; FUNCTIONALIZATIONS; CYCLIZATIONS; QUINOLINES; AMIDATION; ALDEHYDES;

D O I：

10.1002/chem.201801655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In recent years, hydroxylamines derivatives have been exploited as nitrogen-radical precursors in visible-light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen-containing molecules will be highlighted.

引用

页码：12154 / 12163

页数：10

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