Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols

被引：68

作者：

Jérôme, F ^{[1
]}

Monnier, F ^{[1
]}

Lawicka, H ^{[1
]}

Dérien, S ^{[1
]}

Dixneuf, PH ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Chim Rennes, CNRS, UMR 6509, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 06期

关键词：

D O I：

10.1039/b212408d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)(2)(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.

引用

页码：696 / 697

页数：2

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