Hemi(piperazinediium) hexaaqua-aluminium(III) bis(sulfate) tetrahydrate: a redetermination at 100 K

被引：9

作者：

Ghadermazi, Mohammad

Aghabozorg, Hossein ^{[1
]}

Sheshmani, Shabnam

机构：

[1] Teacher Training Univ, Dept Chem, Tehran, Iran

[2] Univ Kurdistan, Dept Chem, Fac Sci, Sanandaj, Iran

[3] Islamic Azad Univ, Dept Chem, Shahre Rey Branch, Tehran, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807028152

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction of aluminium( III) sulfate with piperazinediium pyridine-2,6-dicarboxylate, (pipzH(2))(pydc), where pipz is piperazine and pydcH(2) is pyridine-2,6-dicarboxylic acid, in aqueous solution leads to the formation of the title complex, (C4H12N2)(1/2)[Al(H2O)(6)](SO4)(2) center dot 4H(2)O. The crystal structure of this compound has been published previously [ Bataille ( 2003), Acta Cryst. C59, m459 - m461], and our report is a redetermination of the structure at 100 K. As previously observed, intermolecular O - H center dot center dot center dot O and N - H center dot center dot center dot O hydrogen bonds result in the formation of a three-dimensional network and a supramolecular structure.

引用

页码：M1919 / U1205

页数：9

共 5 条

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Aghabozorg, Hossein ;

Ghadermazi, Mohammad ;

Manteghi, Faranak ;

Nakhjavan, Bahar .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (12-13) :2058-2064

[2]

[Anonymous], 2005, APEX2

[3] Hemi(piperazinediium) hexaapua-aluminium(III) bis(sulfate) tetrahydrate: a new double aluminium sulfate salt [J].

Bataille, T .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 :M459-M461

[4]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565

[5]

Sheldrick G.M., 1998, SHELXTL VERSION 5 10

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