Densities, speeds of sound, isentropic compressibilities, refractive indices and viscosities of binary mixtures of tetrahydrofuran with hydrocarbons at 303.15 K

被引:64
作者
Oswal, SL [1 ]
Gardas, RL [1 ]
Phalak, RP [1 ]
机构
[1] Veer Narmad S Gujarat Univ, Dept Chem, Surat 395007, India
关键词
binary liquid mixtures; hydrocarbon; isentropic compressibility; refractive index; speed of sound; tetrahydrofuran; viscosity;
D O I
10.1016/j.molliq.2004.07.081
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Isentropic compressibilities, Rao's molar sound functions, molar refractions, excess isentropic compressibilities, excess molar volumes, viscosity deviations and excess Gibbs energies of activation of viscous flow for seven binary mixtures of tetrahydrofuran (THF) with cyclohexane, methylcyclohexane, n-hexane, benzene, toluene, p-xylene and propylbenzene over the entire range of composition at 303.15 K have been derived from experimental densities, speeds of sound, refractive indices and viscosities. The excess partial molar volumes of THF in different solvents have been estimated. The experimental results have been analyzed in terms of the Prigogine-Flory-Patterson theory. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:109 / 118
页数:10
相关论文
共 64 条
[21]   EXCESS THERMODYNAMIC QUANTITIES IN BINARY-SYSTEMS OF NON ELECTROLYTES .1. DIFFERENT WAYS OF CALCULATING EXCESS COMPRESSIBILITIES [J].
DOUHERET, G ;
MOREAU, C ;
VIALLARD, A .
FLUID PHASE EQUILIBRIA, 1985, 22 (03) :277-287
[22]   STATISTICAL THERMODYNAMICS OF LIQUID MIXTURES [J].
FLORY, PJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1833-+
[23]   ADIABATIC COMPRESSIBILITIES OF BINARY LIQUID MIXTURES [J].
FORT, RJ ;
MOORE, WR .
TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (514P) :2102-&
[24]   EXCESS-ENTHALPIES AND EXCESS VOLUMES OF BINARY-MIXTURES CONTAINING TOLUENE + CYCLIC ETHERS AT 298.15 K [J].
FRANCESCONI, R ;
COMELLI, F .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1992, 37 (02) :230-232
[25]   Viscosities of the ternary mixture (cyclohexane plus tetrahydrofuran plus chlorocyclohexane) at 298.15 and 313.15 K [J].
Gascón, I ;
Lafuente, C ;
Cea, P ;
Royo, FM ;
Urieta, JS .
FLUID PHASE EQUILIBRIA, 1999, 164 (01) :143-155
[26]   SURFACE-TENSION EFFECTS IN SUSPENDED-LEVEL CAPILLARY VISCOMETERS [J].
GONCALVES, FA ;
KESTIN, J ;
SENGERS, JV .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1991, 12 (06) :1013-1028
[27]   EXCESS ENTHALPIES AND EXCESS VOLUMES OF N-HEXANE + AND OF TETRACHLOROMETHANE + FURAN, + 1,4-DIOXANE, + TETRAHYDROFURAN, AND + TETRAHYDROPYRAN [J].
GUILLEN, MD ;
GUTIERREZLOSA, C .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1978, 10 (06) :567-576
[28]   LIQUID DENSITIES FROM 293 TO 490 K OF 9 AROMATIC-HYDROCARBONS [J].
HALES, JL ;
TOWNSEND, R .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1972, 4 (05) :763-&
[29]   THERMODYNAMICS OF BINARY-MIXTURES CONTAINING CYCLIC ETHERS .3. EXCESS-ENTHALPIES OF OXOLANE, 1,3-DIOXOLANE, OXANE, AND 1,3-DIOXANE + BENZENE AND + TETRACHLOROMETHANE [J].
INGLESE, A ;
WILHELM, E ;
GROLIER, JPE ;
KEHIAIAN, HV .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1981, 13 (03) :229-234
[30]   EXCESS MOLAR VOLUMES OF METHYLCYCLOHEXANE+BENZENE, +METHYLBENZENE, +1,4-DIOXANE, AND +TETRAHYDROFURAN AT 303.15K [J].
JAIN, DVS ;
SINGLA, VK ;
SAINI, SB ;
SIDHU, RS .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1983, 15 (12) :1105-1107