1,8-naphthalimides as blue emitting fluorophores for polymer materials

被引：56
作者：
Grabchev, I
Petkov, C
Bojinov, V
机构：
[1] Univ Chem Technol & Met, Dept Organ Synth, BU-1756 Sofia, Bulgaria
[2] Bulgarian Acad Sci, Inst Polymers, BU-1113 Sofia, Bulgaria
[3] Bulgarian Customs Agcy, Cent Customs Lab, Sofia 1113, Bulgaria
来源：
MACROMOLECULAR MATERIALS AND ENGINEERING | 2002年 / 287卷 / 12期
关键词：
blue fluorescent polyacrylonitrile; fluorescent brighteners; FT-IR spectroscopy; 1,8-naphthalimide; photostability; polymerizable fluorophore;
D O I：
10.1002/mame.200290025
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The copolymerization of 1,8-naththalimide derivatives (as fluorophore) with acrylonitrile has been investigated. The photophysical characteristics of monomeric and polymeric fluorophores in N,N-dimethylformamide solution have been determined and discussed. During copolymerization, no changes in the chromophoric systems of the fluorophore occur. The influence of the studied monomeric 1,8-naphthalimide fluorophores upon the structurally bleached polyacrylonitrile has been determined. Infrared adsorption characteristics of the polymerizable 4-alkoxy-and 4-allyloxy-N-substituted 1,8-naphthalimides have been measured and discussed. The effect of the substituents upon the vibration frequencies of the carbonyl and allylic groups has been established.
引用
收藏
页码：904 / 908
页数：5
相关论文
共 23 条
[1]   A new method for synthesis of 4-allyloxy-1,8-naphthalimide derivatives for use as fluorescent brighteners [J].
Bojinov, V ;
Grabchev, I .
DYES AND PIGMENTS, 2001, 51 (01) :57-61
[2]  
Gordon PF, 1987, Organic Chemistry in Colour
[3]  
Springer Study Edition
[4]   Synthesis and characterisation of fluorescent polyacrylonitrile copolymers with 1,8-naphthalimide side chains [J].
Grabchev, I ;
Bojinov, V .
POLYMER DEGRADATION AND STABILITY, 2000, 70 (02) :147-153
[5]  
Grabchev I, 1999, J APPL POLYM SCI, V74, P151, DOI 10.1002/(SICI)1097-4628(19991003)74:1<151::AID-APP19>3.0.CO
[6]  
2-A
[7]   Synthesis of some polymerisable 1,8-naphthalimide derivatives for use as fluorescent brighteners [J].
Grabchev, I ;
Konstantinova, T .
DYES AND PIGMENTS, 1997, 33 (03) :197-203
[8]  
Grabchev I, 1999, ANGEW MAKROMOL CHEM, V269, P49
[9]   Copolymerization and photo stabilization of methylmethacrylate with 1,8-naphthalimide fluorescent brighteners [J].
Grabchev, I ;
Betcheva, R .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 142 (01) :73-78
[10]   Photophysical and photochemical properties of blue fluorescent polystyrene [J].
Grabchev, I ;
Bojinov, V .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 139 (2-3) :157-160
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