1,8-naphthalimides as blue emitting fluorophores for polymer materials

被引：56

作者：

Grabchev, I

Petkov, C

Bojinov, V

机构：

[1] Univ Chem Technol & Met, Dept Organ Synth, BU-1756 Sofia, Bulgaria

[2] Bulgarian Acad Sci, Inst Polymers, BU-1113 Sofia, Bulgaria

[3] Bulgarian Customs Agcy, Cent Customs Lab, Sofia 1113, Bulgaria

来源：

MACROMOLECULAR MATERIALS AND ENGINEERING | 2002年 / 287卷 / 12期

关键词：

blue fluorescent polyacrylonitrile; fluorescent brighteners; FT-IR spectroscopy; 1,8-naphthalimide; photostability; polymerizable fluorophore;

D O I：

10.1002/mame.200290025

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The copolymerization of 1,8-naththalimide derivatives (as fluorophore) with acrylonitrile has been investigated. The photophysical characteristics of monomeric and polymeric fluorophores in N,N-dimethylformamide solution have been determined and discussed. During copolymerization, no changes in the chromophoric systems of the fluorophore occur. The influence of the studied monomeric 1,8-naphthalimide fluorophores upon the structurally bleached polyacrylonitrile has been determined. Infrared adsorption characteristics of the polymerizable 4-alkoxy-and 4-allyloxy-N-substituted 1,8-naphthalimides have been measured and discussed. The effect of the substituents upon the vibration frequencies of the carbonyl and allylic groups has been established.

引用

页码：904 / 908

页数：5

共 23 条

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