Synthesis, structure and magnetism of [Nd(ONO2)6][Cu(Im)(phen)2]2(OH)•4H2O

The crystal of [Nd(ONO2)(6)][Cu(Im)(phen)(2)](2)(OH). 4H(2)O was synthesized and its structure of its single crystal was determined by X-ray diffraction. The crystal is triclinic system, space group P1 with a=1.012 6(2) nm, b=1.179 2(2) nm, c=1.398 5 nm, alpha=111.32(3)degrees, beta=93.17(3)degrees, gamma=90.33(3), V=1.552 6(5) nm(3), Z=1, D-c=1.700 g/cm(3), F(000)=801, R=0.043, R-w=0.070. UV-Vis-NIR, IR and magnetic susceptibility were determined and-the related properties of the complex were discussed, It is found that the title complex possesses the behavior of anti-ferromagnetic material at low-temperature.