LiSr2(NCN)I3:: the first empty tetrahedral strontium(II) entity coordinated by carbodiimide units but without strontium-strontium bonding

被引:9
作者
Liao, WP [1 ]
von Appen, J [1 ]
Dronskowski, R [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
关键词
D O I
10.1039/b408647c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
LiSr2(NCN)I-3, the first extended compound containing empty tetrahedral Sr-4 entities, is synthesized using a new flux route, and it exhibits two interpenetrating three-dimensional networks made up from Sr tetrahedra capped by NCN2- anions on their triangular faces and vertex-sharing LiI6 octahedra.
引用
收藏
页码:2302 / 2303
页数:2
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