Synthesis and hydrogen adsorption properties of a new phthalocyanine-based metal-organic framework

被引:12
|
作者
Lee, Chi-Hang [1 ]
Filler, Robert [1 ,2 ]
Lee, JeongYong [3 ]
Li, Jing [3 ]
Mandal, Braja K. [1 ]
机构
[1] IIT, Dept Biol Chem & Phys Sci, Chicago, IL 60616 USA
[2] TechDrive Inc, Chicago, IL 60616 USA
[3] Rutgers State Univ, Dept Chem & Biol Chem, Piscataway, NJ 08854 USA
关键词
Hydrogen storage; Hydrogen adsorption; Metal-organic frameworks; Phthalocyanines; MOLECULAR-HYDROGEN; INFRARED CHARACTERIZATION; ARGON MATRICES; DIHYDROGEN; STORAGE; PHYSISORPTION; HALIDES; CATION; GASES;
D O I
10.1016/j.renene.2010.01.012
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The first member of a new class of phthalocyanine-based metal-organic frameworks, MOF-IP, has been synthesized in order to gauge the potential of this type of materials for hydrogen storage. Preliminary studies indicate that MOF-IP is a robust material with a hydrogen uptake capacity of 1.15 wt% at 77 K under atmospheric pressure. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1592 / 1595
页数:4
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