An Infinite 2D Supramolecular Cobalt(II) Complex Based on an Asymmetric Salamo-Type Ligand: Synthesis, Crystal Structure, and Spectral Properties

被引：82

作者：

Wang, Ping ^{[1
]}

Zhao, Li ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 07期

关键词：

asymmetric Salamo-type ligand; Co(II) complex; synthesis; crystal structure; spectral property; SPECTROSCOPIC PROPERTIES; MAGNETIC-PROPERTIES; COPPER(II); ZINC(II);

D O I：

10.1080/15533174.2015.1004416

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Co() complex, [Co-2(L)(2)]CH3COCH3 based on an asymmetric Salamo-type ligand (H2L, 5-methoxy-4',6'-dibromo-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol) has been synthesized and characterized structurally by elemental analyses, IR, UV-Vis, and fluorescence spectra. The X-ray crystal structure shows the Co(II) ion is pentacoordinated with geometry of a distorted square-pyramidal symmetry. The Co() complex consists of two Co() ions, two deprotonated L2- units, and one noncoordinated acetone molecule. Each Co() complex molecule links four other molecules into an infinite 2D supramolecular structure. Meanwhile, the Co(II) complex exhibits emission with the maximum emission wavelength (max) = 432nm when excited at (ex) = 349nm.

引用

页码：1095 / 1101

页数：7

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