Novel reactions of extremely hindered plumbylenes with elemental sulfur and carbon disulfide

被引：0

作者：

Tokitoh, N ^{[1
]}

Kano, N ^{[1
]}

Okazaki, R ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 153卷

关键词：

plumbylenes; kinetic stabilization; elemental sulfur; 1,2-aryl migration; plumbanethione; carbon disulfide;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis, structure, and some reactivities of kinetically stabilized plumbylenes are described. The reaction of an extremely hindered plumbylene Tbt(2)Pb: (Tbt= 2,4,6-tris[bis(trimethylsilyl)methyl]pheyl with elemental sulfur gave Tbt(TbtS)Pb: via an interesting 1,2-aryl migration of the intermediary plumbanethione, Tbt(2)Pb=S. The reactions of overcrowded aryl(arylthio)plumbylenes and bis(arylthio)-plumbylenes with carbon disulfide are also described.

引用

页码：333 / 334

页数：2