Stable trifluoromethylated fullerene radicals C60(CF3)15 and C60(CF3)17

被引:9
作者
Vorobiev, Andrey Kh. [1 ]
Markov, Vitaly Yu. [1 ]
Samokhvalova, Nadezhda A. [1 ]
Samokhvalov, Pavel S. [1 ]
Troyanov, Sergey I. [1 ]
Sidorov, Lev N. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
CRYSTAL-STRUCTURE; DERIVATIVES; ESR; FLUORINATION; SPECTRA; C-60;
D O I
10.1016/j.mencom.2010.01.003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Stable C-60(CF3)(15) and C-60(CF3)(17) radicals were generated by UV irradiation of C-60(CF3)(n) mixture and characterized by ESR spectroscopy and MALDI mass spectrometry revealing the presence of pentakis- and tris(tfifluoromethyl) moieties, respectively.
引用
收藏
页码:7 / 9
页数:3
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