Copper corrosion in bentonite/saline groundwater solution: Effects of solution and bentonite chemistry

被引:59
作者
Kosec, T. [1 ]
Qin, Z. [2 ]
Chen, J. [2 ]
Legat, A. [1 ]
Shoesmith, D. W. [2 ,3 ]
机构
[1] Slovenian Natl Bldg & Civil Engn Inst, SI-1000 Ljubljana, Slovenia
[2] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
[3] Univ Western Ontario, London, ON N6G 0J3, Canada
关键词
Copper; EIS; Raman spectroscopy; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; SITU RAMAN-SPECTROSCOPY; 3-PERCENT NACL; FILM FORMATION; SULFIDE; OXIDATION; CHLORIDE; BENZOTRIAZOLE; MECHANISMS; PRODUCTS;
D O I
10.1016/j.corsci.2014.10.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Copper corrosion has been studied in simulated groundwater with and without added bentonite clay using different electrochemical techniques. The corroded surfaces were characterised by SEM/EDS, Raman spectroscopy and Auger depth profiling. In both environments small amounts of sulphide (0.005 mM) control the early corrosion behaviour. Under aerated conditions an initially formed Cu2S film is rapidly converted to a non-protective layer of cuprite and corrosion proceeds with the deposition of an outer layer of atacamite. In the presence of bentonite corrosion proceeds slowly under O-2 transport control. No atacamite is observed and the Cu surface appears slightly pitted. (C) 2014 Published by Elsevier Ltd.
引用
收藏
页码:248 / 258
页数:11
相关论文
共 50 条
[1]   Rapid intergranular corrosion of copper in sulfide-polluted salt water [J].
Al Kharafi, F. M. ;
Ghayad, I. M. ;
Ateya, B. G. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (04) :G15-G18
[2]   Effect of sulfide pollution on the stability of the protective film of benzotriazole on copper [J].
Al Kharafi, F. M. ;
Abdullah, A. M. ;
Ghayad, I. M. ;
Ateya, B. G. .
APPLIED SURFACE SCIENCE, 2007, 253 (22) :8986-8991
[3]  
Alkharafi FM, 2009, INT J ELECTROCHEM SC, V4, P1351
[4]   Effects of benzotriazole on the corrosion of Cu10Ni alloy in sulfide-polluted salt water [J].
Allam, NK ;
Ashour, EA ;
Hegazy, HS ;
El-Anadouli, BE ;
Ateya, BG .
CORROSION SCIENCE, 2005, 47 (09) :2280-2292
[5]  
[Anonymous], 2007, CORROSION ENG HDB
[6]  
Barsoukov E, 2005, IMPEDANCE SPECTROSCOPY: THEORY, EXPERIMENT, AND APPLICATIONS, 2ND EDITION, pXII
[7]   Corrosion of copper in simulated nuclear waste repository conditions [J].
Betova, I ;
Beverskog, BR ;
Bojinov, M ;
Kinnunen, P ;
Mäkelä, K ;
Pettersson, SO ;
Saario, T .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (04) :B19-B22
[8]   A mechanism of interaction of copper with a deoxygenated neutral aqueous solution [J].
Bojinov, Martin ;
Betova, Iva ;
Lilja, Christina .
CORROSION SCIENCE, 2010, 52 (09) :2917-2927
[9]   THE ANALYSIS OF ELECTRODE IMPEDANCES COMPLICATED BY THE PRESENCE OF A CONSTANT PHASE ELEMENT [J].
BRUG, GJ ;
VANDENEEDEN, ALG ;
SLUYTERSREHBACH, M ;
SLUYTERS, JH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 176 (1-2) :275-295
[10]   Oxide film formation and oxygen adsorption on copper in aqueous media as probed by surface-enhanced Raman spectroscopy [J].
Chan, HYH ;
Takoudis, CG ;
Weaver, MJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (02) :357-365