Temperature-controlled combustion and kinetics of different rank coal samples

被引:114
|
作者
Kök, MV [1 ]
机构
[1] Middle E Tech Univ, Dept Petr & Nat Gas Engn, TR-06531 Ankara, Turkey
关键词
coal; differential scanning calorimetry; lignite; reaction kinetics; thermal analysis; thermogravimetry;
D O I
10.1007/s10973-004-0581-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
Differential scanning calorimetry (DSC) and thermogravimetry (TG/DTG) has been used to obtain information on the temperature-controlled combustion characteristics of seventeen coals of different origin from Thrace basin of Turkey. Experiments were performed in air atmosphere up to 600degreesC at a heating rate of 10degrees min(-1). The DSC/TG curves clearly demonstrate distinct transitional stages in the entire coal samples studied. Reaction intervals, peak and burn-out temperatures of the coal samples are also determined. Two different kinetic methods known as, Arrhenius and Coats-Redfern, were used to analyze the kinetic data and the results are discussed.
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页码:175 / 180
页数:6
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