SYNTHESIS AND CHARACTERIZATION OF NOVEL M(II) (M = Mn(II), Ni(II), Cu(II) OR Zn(II)) COMPLEXES WITH TRIDENTATE N2,O-DONOR LIGAND (E)-2-AMINO-N′-[1-(PYRIDIN-2-YL) ETHYLIDENE]BENZOHYDRAZIDE

被引：5

作者：

Kane, Cheikh Hamidou ^{[1
]}

Tinguiano, Daniel ^{[1
]}

Tamboura, Farba Bouyagui ^{[1
]}

Thiam, Ibrahima Elhadj ^{[1
]}

Barry, Aliou Hamady ^{[2
]}

Gaye, Mohamed ^{[1
]}

Retailleau, Pascal ^{[3
]}

机构：

[1] Univ Cheikh Anta Diop, Dept Chem, Dakar, Senegal

[2] Univ Nouakchott, Dept Chem, Mauritania, Mauritania

[3] CNRS, Inst Chim Subst Nat, UPR2301, Ctr Rech Gif, 1 Ave Terrasse, F-91198 Gif Sur Yvette, France

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2016年 / 30卷 / 01期

关键词：

Schiff base; Phenolate; Manganese(II); Nickel(II); Copper(II); Zinc(II); Mononuclear complexes; X-Ray structure; DONOR SCHIFF-BASE; TRANSITION-METAL-COMPLEXES; X-RAY CRYSTAL; COPPER(II) COMPLEXES; SPECTRAL CHARACTERIZATION; MOLECULAR-STRUCTURE;

D O I：

10.4314/bese.v30i1.9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination chemistry towards the M(II) metal centre (M = Mn, Ni, Cu or Zn) of the hydrazone ligand (E)-2-amino-N'-[1-(pyridin-2-yl)ethylidene]benzohydrazide (H3L) has been explored and complexes having formulae [Mn(H2L)(2)](1), {[Ni(H2L)(2)]center dot DMF center dot 0.4H(2)O}(2), {[Cu-2(H2L)(2)(mu-Cl)(2)]center dot DMF} (3) and [Zn(H2L)(2)] ( 4) have been isolated and characterized by IR, UV-Visible spectroscopy, elemental analysis and Xray crystal diffraction. Structural studies reveal that the mononuclear complexes (1), (2) and (4) adopt highly distorted octahedral geometries while the dinuclear complex (3) adopts a square pyramidal geometry around each copper(II) ion.

引用

页码：101 / 110

页数：10

共 31 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].