Electrochemical synthesis of lepidocrocite thin films on gold substrate -: EQCM, IRRAS, SEM and XRD study

被引：48

作者：

Antony, H ^{[1
]}

Peulon, S ^{[1
]}

Legrand, L ^{[1
]}

Chaussé, K ^{[1
]}

机构：

[1] Univ DEvry Val DEssonne, CNRS, Lab Anal & Environm, CEA,UMR 8587, F-91025 Evry, France

来源：

ELECTROCHIMICA ACTA | 2004年 / 50卷 / 04期

关键词：

lepidocrocite; thin film; electrochemical synthesis; IRRAS; orientation;

D O I：

10.1016/j.electacta.2004.07.043

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Lepidocrocite thin films have been electrochemically synthesised on polycrystalline Au substrates following two ways, direct synthesis and synthesis via green rust (GR). The direct synthesis consists in oxidising Fe(II) species in a 0.4 M NaCl/0.02 M Met-Imidazole/0.01 M FeCl2 solution at pH 7.5. The synthesis via GR consists in converting a green rust thin film into lepidocrocite thin film by galvanostatic oxidation. The thin films have been characterised by means of electrochemical quartz crystal microbalance, scanning electron microscopy, X-ray diffraction and infrared reflection-absorption spectroscopy. (C) 2004 Published by Elsevier Ltd.

引用

页码：1015 / 1021

页数：7

共 24 条

[1] ANODIC DEPOSITION OF GAMMA-FEOOH LAYERS ON INERT METAL-ELECTRODES [J].

ARDIZZONE, S ;

FORMARO, L .

SURFACE TECHNOLOGY, 1983, 19 (02) :119-127

[2] AN ELECTROCHEMICAL STUDY OF THE ATMOSPHERIC CORROSION OF MILD-STEEL .1. EXPERIMENTAL-METHOD [J].

COX, A ;

LYON, SB .

CORROSION SCIENCE, 1994, 36 (07) :1167-1176

[3] Structural comparison between Cu(OH)2(s) and γ- FeO(OH)(s) [J].

Cudennec, Y ;

Lecerf, A .

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2001, 4 (12) :885-891

[4] MECHANISM OF ATMOSPHERIC RUSTING [J].

EVANS, UR ;

TAYLOR, CAJ .

CORROSION SCIENCE, 1972, 12 (03) :227-&

[5] ANODIC DEPOSITION OF FERRIC OXYHYDROXIDE FILMS ON PLATINUM FROM PERCHLORATE SOLUTIONS [J].

HASHIMOTO, K ;

COHEN, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1974, 121 (01) :37-42

[6] Advances in understanding atmospheric corrosion of iron. II. Mechanistic modelling of wet-dry cycles [J].

Hoerle, S ;

Mazaudier, F ;

Dillmann, P ;

Santarini, G .

CORROSION SCIENCE, 2004, 46 (06) :1431-1465

[7] Study of oxidation products formed on iron in solutions containing bicarbonate/carbonate [J].

Legrand, L ;

Savoye, S ;

Chausse, A ;

Messina, R .

ELECTROCHIMICA ACTA, 2000, 46 (01) :111-117

[8] The oxidation of carbonate green rust into ferric phases:: solid-state reaction or transformation via solution [J].

Legrand, L ;

Mazerolles, L ;

Chaussé, A .

GEOCHIMICA ET COSMOCHIMICA ACTA, 2004, 68 (17) :3497-3507

[9] Reduction of aqueous chromate by Fe(11)/Fe(111) carbonate green rust: Kinetic and mechanistic studies [J].

Legrand, L ;

EL Figuigui, A ;

Mercier, F ;

Chausse, A .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (17) :4587-4595

[10] Electroanalytical and kinetic investigations on the carbonate green rust-Fe(III) redox system [J].

Legrand, L ;

Maksoub, R ;

Sagon, G ;

Lecomte, S ;

Dallas, JP ;

Chaussé, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :B45-B51

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