A novel helical copper complex:: catena-poly[[[aquacopper(II)]-μ-N-(3-carboxy-2-oxidobenzyl-idene-κO2)glycinato-κ3N,O′:O′] monohydrate]

被引:2
作者
Cai, Jin-Hua [1 ]
Wu, Zhi-Hong
Huang, Ying-Heng
Yin, Xu-Ju
Jiang, Yi-Min
机构
[1] Hechi Univ, Dept Chem & Life Sci, Guangxi 546300, Yizhou, Peoples R China
[2] Guangxi Normal Univ, Dept Chem, Guangxi 541000, Guilin, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷
关键词
D O I
10.1107/S0108270107019312
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the polymeric title compound, {[Cu(C10H7NO5)(H2O)]H2O}(n), the Cu atom adopts a square-based pyramidal coordination involving a N,O,O'-tridentate glycine dianionic ligand, a water O atom and an apical bridging carboxylate O atom from an adjacent ligand. The title compound also adopts a carboxylate-bridged chain structure. The molecular chain propagates in a helical fashion along the b axis of the monoclinic unit cell. Neighbouring chains are linked together to form a three-dimensional network via hydrogen-bonding interactions between coordinated and uncoordinated water molecules and O atoms of the bridging carboxylate groups.
引用
收藏
页码:M267 / M269
页数:3
相关论文
共 16 条
[1]  
*BRUK AXS INC, 1999, SMART VERS 6 36A SAI
[2]  
*BRUK AXS INC, 1997, SHELXTL VERS 5 10
[3]   catena-poly[[(pyridine-κN)copper(II)]-μ-N-salicylideneglycinato-κ4O,N,O′:O′] [J].
Butcher, RJ ;
Mockler, GM ;
McKern, O .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 :M1104-M1106
[4]   catena-Poly[[[(pyridine-κN)copper(II)]-μ-N-(3-carboxysalicylidene)glycinato-κ4N,O,O′:O′] monohydrate] [J].
Cai, Jin-Hua ;
Huang, Ying-Heng ;
Jiang, Yi-Min ;
ng, Seik We Ng .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :M2823-M2825
[5]  
Chen XM, 2002, CHEM-EUR J, V8, P4811, DOI 10.1002/1521-3765(20021018)8:20<4811::AID-CHEM4811>3.0.CO
[6]  
2-R
[7]   Interlocked chiral nanotubes assembled from quintuple helices [J].
Cui, Y ;
Lee, SJ ;
Lin, WB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6014-6015
[8]   Synthesis and structure of {[Ag(SalGly)]•0.33H2O}n:: An infinite double helical coordination polymer [J].
Erxleben, A .
INORGANIC CHEMISTRY, 2001, 40 (12) :2928-2931
[9]   A chiral coordination polymer containing copper(I) iodide layer composed of intersecting [CuI]n helices [J].
Peng, R ;
Wu, T ;
Li, D .
CRYSTENGCOMM, 2005, 7 :595-598
[10]   A new type of single-helix coordination polymer with mixed ligands [M2(phen)2(e,a-cis-1,4-chdc)2(H2O)2]n (M = Co and Ni;: phen 1,10-phenanthroline; chdc = cyclohexanedicarboxylate) [J].
Qi, YJ ;
Wang, YH ;
Hu, CW ;
Cao, MH ;
Mao, L ;
Wang, EB .
INORGANIC CHEMISTRY, 2003, 42 (25) :8519-8523