CNTs nanostructuring effect on the properties of graphite composite bipolar plate

被引:67
作者
Dhakate, S. R. [1 ]
Sharma, S. [1 ]
Chauhan, N. [1 ]
Seth, R. K. [1 ]
Mathur, R. B. [1 ]
机构
[1] CSIR, Natl Phys Lab, Engn Mat Div, Carbon Technol Unit, New Delhi 110012, India
关键词
Bipolar plate; Nanocomposite; Electrical conductivity; Thermal conductivity; FUEL-CELL; CARBON NANOTUBES; MECHANICAL-PROPERTIES;
D O I
10.1016/j.ijhydene.2010.02.072
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Intent of present investigation is to improve the properties of graphite-polymer composite bipolar plate by nanostructuring. This involves the incorporation of different vol.% of multiwall carbon nanotubes (MWNTs) in graphite-polymer composite bipolar plate. It has been found that by inclusion of 1 vol.% of MWNTs in graphite composite plate, the electrical and thermal conductivity of nanocomposite increased by 100%. The thermal conductivity of nanocomposite plate increases from 1 W/m K to 13 W/m K in through-plane and in-plane from 25 W/m K to 50 W/m K at 1 vol.% of MWNTs. This significant enhancement is due to the orientation of MWNTs in all the directions of composite, positive synergistic effect of MWNTs and heat transfer along the axis directions. However, bending strength of nanocomposite increases by 25% and maximum augmentation is in case of 1 vol.% of MWNTs. The improvement in conductivity of nanocomposite plate is due to an increase in the electron transfer ability within the composite plate which influences the I-V performance of ultimate fuel cell. These observations confirm that the optimal content of MWNTs is 1 vol.%, in graphite-polymer composite. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:4195 / 4200
页数:6
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