Formation of Cyclic Carbonates from CO2 and Epoxides Catalyzed by a Cobalt-Coordinated Conjugated Microporous Polymer

被引：25

作者：

Xiong, Jian ^{[1
,2
]}

Yang, Rui-Xia ^{[2
]}

Xie, Yong ^{[2
]}

Huang, Nian-Yu ^{[1
]}

Zou, Kun ^{[1
]}

Deng, Wei-Qiao ^{[2
]}

机构：

[1] China Three Gorges Univ, Coll Biol & Pharm, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, \ Dalian 116023, Peoples R China

来源：

CHEMCATCHEM | 2017年 / 9卷 / 13期

关键词：

carbon dioxide; cyclic carbonates; heterogeneous catalysis; high-efficiency; microporous materials; HETEROGENEOUS CATALYST; PROPYLENE CARBONATE; ETHYLENE CARBONATE; DIOXIDE; FRAMEWORKS; EFFICIENT; FIXATION; OXIDE; COPOLYMERIZATION; CYCLOADDITION;

D O I：

10.1002/cctc.201700386

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An inexpensive and effective cobalt coordinated conjugated microporous polymer (Co-CMP-2) made up from cross-linked an ethanediamine-based salen ligand with 1,3,5-triethynylbenzene. Co-CMP-2 exhibited extremely high catalytic efficiency in the synthesis of cyclic carbonates from CO2 and epoxides, which is superior to that of previously reported Co-CMP. Co-CMP-2 achieved a TOF of 23300 h(-1) for ethylene carbonate. Moreover, the catalyst can be reused more than 10 times without significant loss in activity.

引用

页码：2584 / 2587

页数：4

共 53 条

[51] Magnesium oxide-catalysed reaction of carbon dioxide with an epoxide with retention of stereochemistry
Yano, T
Matsui, H
Koike, T
Ishiguro, H
Fujihara, H
Yoshihara, M
Maeshima, T
[J]. CHEMICAL COMMUNICATIONS, 1997, (12) : 1129 - 1130
[52] Intramolecularly two-centered cooperation catalysis for the synthesis of cyclic carbonates from CO2 and epoxides
Zhang, Xiang
Jia, Yin-Bao
Lu, Xiao-Bing
Li, Bo
Wang, Hui
Sun, Li-Cheng
[J]. TETRAHEDRON LETTERS, 2008, 49 (46) : 6589 - 6592
[53] Functional porous organic polymers for heterogeneous catalysis
Zhang, Yugen
Riduan, Siti Nurhanna
[J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) : 2083 - 2094

← 1 2 3 4 5 6 →