Formation of Cyclic Carbonates from CO2 and Epoxides Catalyzed by a Cobalt-Coordinated Conjugated Microporous Polymer

被引：25
作者：
Xiong, Jian [1 ,2 ]
Yang, Rui-Xia [2 ]
Xie, Yong [2 ]
Huang, Nian-Yu [1 ]
Zou, Kun [1 ]
Deng, Wei-Qiao [2 ]
机构：
[1] China Three Gorges Univ, Coll Biol & Pharm, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, \ Dalian 116023, Peoples R China
来源：
CHEMCATCHEM | 2017年 / 9卷 / 13期
关键词：
carbon dioxide; cyclic carbonates; heterogeneous catalysis; high-efficiency; microporous materials; HETEROGENEOUS CATALYST; PROPYLENE CARBONATE; ETHYLENE CARBONATE; DIOXIDE; FRAMEWORKS; EFFICIENT; FIXATION; OXIDE; COPOLYMERIZATION; CYCLOADDITION;
D O I：
10.1002/cctc.201700386
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An inexpensive and effective cobalt coordinated conjugated microporous polymer (Co-CMP-2) made up from cross-linked an ethanediamine-based salen ligand with 1,3,5-triethynylbenzene. Co-CMP-2 exhibited extremely high catalytic efficiency in the synthesis of cyclic carbonates from CO2 and epoxides, which is superior to that of previously reported Co-CMP. Co-CMP-2 achieved a TOF of 23300 h(-1) for ethylene carbonate. Moreover, the catalyst can be reused more than 10 times without significant loss in activity.
引用
收藏
页码：2584 / 2587
页数：4
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