Liquid order at the interface of KDP crystals with water: Evidence for icelike layers

被引：99

作者：

Reedijk, MF

Arsic, J

Hollander, FFA

de Vries, SA

Vlieg, E

机构：

[1] Univ Nijmegen, NSRIM, Dept Solid State Chem, NL-6525 ED Nijmegen, Netherlands

[2] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands

来源：

PHYSICAL REVIEW LETTERS | 2003年 / 90卷 / 06期

关键词：

D O I：

10.1103/PhysRevLett.90.066103

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We present a surface x-ray diffraction study on the KDP-water interface in which the structure of both the crystalline and liquid part of the interface has been measured. We have been able to determine the ordering components in the liquid in both the perpendicular and parallel directions. We find interface-induced ordering in the first four layers of water molecules. The first two layers behave icelike and are strongly bound to the surface. The next two layers are more diffuse and show only minor lateral and perpendicular ordering. Subsequent layers are found to behave similar to a bulk liquid.

引用

收藏

页码：4 / 066103

页数：4

相关论文

共 28 条

[1] High-resolution in-situ transmission electron microscopy observation of a solid-liquid interface in the Al-Si system [J].

Arai, S ;

Tsukimoto, S ;

Miyai, H ;

Saka, H .

JOURNAL OF ELECTRON MICROSCOPY, 1999, 48 (04) :317-321

[2] Molecular-scale density oscillations in water adjacent to a mica surface [J].

Cheng, L ;

Fenter, P ;

Nagy, KL ;

Schlegel, ML ;

Sturchio, NC .

PHYSICAL REVIEW LETTERS, 2001, 87 (15) :156103-156103

[3] Commensurate water monolayer at the RuO2(110)/water interface [J].

Chu, YS ;

Lister, TE ;

Cullen, WG ;

You, H ;

Nagy, Z .

PHYSICAL REVIEW LETTERS, 2001, 86 (15) :3364-3367

[4] Simulation of the hard-sphere crystal-melt interface [J].

Davidchack, RL ;

Laird, BB .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (22) :9452-9462

[5] Surface atomic structure of KDP crystals in aqueous solution: An explanation of the growth shape [J].

de Vries, SA ;

Goedtkindt, P ;

Bennett, SL ;

Huisman, WJ ;

Zwanenburg, MJ ;

Smilgies, DM ;

De Yoreo, JJ ;

van Enckevort, WJP ;

Bennema, P ;

Vlieg, E .

PHYSICAL REVIEW LETTERS, 1998, 80 (10) :2229-2232

[6] Developing KH2PO4 and KD2 PO4 crystals for the world's most powerful laser [J].

De Yoreo, JJ ;

Burnham, AK ;

Whitman, PK .

INTERNATIONAL MATERIALS REVIEWS, 2002, 47 (03) :113-152

[7] GROWTH-MORPHOLOGY OF VICINAL HILLOCKS ON THE (101) FACE OF KH2PO4 - FROM STEP-FLOW TO LAYER-BY-LAYER GROWTH [J].

DEYOREO, JJ ;

LAND, TA ;

DAIR, B .

PHYSICAL REVIEW LETTERS, 1994, 73 (06) :838-841

[8] PB/GE(111)1X1 - AN ANISOTROPIC 2-DIMENSIONAL LIQUID [J].

GREY, F ;

FEIDENHANS, R ;

PEDERSEN, JS ;

NIELSEN, M ;

JOHNSON, RL .

PHYSICAL REVIEW B, 1990, 41 (13) :9519-9522

[9] IMAGING THE CONDENSATION AND EVAPORATION OF MOLECULARLY THIN-FILMS OF WATER WITH NANOMETER RESOLUTION [J].

HU, J ;

XIAO, XD ;

OGLETREE, DF ;

SALMERON, M .

SCIENCE, 1995, 268 (5208) :267-269

[10] Layering of a liquid metal in contact with a hard wall [J].

Huisman, WJ ;

Peters, JF ;

Zwanenburg, MJ ;

deVries, SA ;

Derry, TE ;

Abernathy, D ;

vanderVeen, JF .

NATURE, 1997, 390 (6658) :379-381