Unveiling reliable catalysts for the asymmetric nitroaldol (Henry) reaction

被引：298

作者：

Palomo, C ^{[1
]}

Oiarbide, M ^{[1
]}

Mielgo, A ^{[1
]}

机构：

[1] Univ Basque Country, Fac Quim, Dept Quim Organ 1, San Sebastian 20080, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 41期

关键词：

asymmetric catalysis; C-C bond formation; Henry reaction; nitroaldol reaction; synthetic methods;

D O I：

10.1002/anie.200460506

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conceptually different chiral catalysts ranging from polymetallic complexes to Lewis acids and organocatalysts have emerged for solving the long-standing problem of stereocontrol in the Henry reaction, a fundamental C-C bond-forming process (see scheme). New catalyst systems with improved selectivity have increased the synthetic value of this reaction considerably.

引用

页码：5442 / 5444

页数：3

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